Process of producing high molecular weight ethylene-.alpha.-olefin elastomers with an indenyl metallocene catalyst system
AssigneeExxon Chemical Patents Inc.
InventorElvin L. Hoel
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AssigneeExxon Chemical Patents Inc.
InventorElvin L. Hoel
Estimating the term…
Disclosed is a process for preparing high molecular weight ethylene-.alpha.-olefin elastomers, preferably an ethylene-propylene elastomer, by liquid phase polymerization of the requisite monomers in the presence of a metallocene/alumoxane catalyst complex. Preferably, the process is carried out as a slurry polymerization utilizing the metallocene/alumoxane catalyst in supported form on a silica gel support with the .alpha.-olefin monomer maintained in liquid state and used in excess to serve as a polymerization diluent. The metallocene component of the catalyst by which the process is practiced is of the formula: ##STR1## wherein M is zirconium, titanium or hafnium; R.sup.1 and R.sup.2 are independently a C.sub.1 -C.sub.20 linear, branched or cyclic alkyl group; X an alkyl, aryl, halide, hydride or oxygen bridge of a zirconocene dimer; "y" and "z" are independently numbers 0, 1 or 2; and M is preferably zirconium. Most preferably, the supported zirconocene/alumoxane catalyst is prepolymerized with ethylene or another olefin to provide spherical, free-flowing catalyst particles which give free-flowing particulate elastomer product from the slurry polymerization.
A process for producing an ethylene/.alpha.-olefin elastomeric copolymer in slurry polymerization, comprising the steps of:
A process for producing an ethylene/.alpha.-olefin elastomeric copolymer in slurry polymerization, comprising the steps of:
Dependencies are inferred from the claim text.