Oxidation catalyst with bulk ceria, a second bulk metal oxide, and platinum
AssigneeEngelhard Corporation
InventorsKenneth E. Voss, Bulent O. Yavuz, Robert J. Farrauto, Michael P. Galligan
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AssigneeEngelhard Corporation
InventorsKenneth E. Voss, Bulent O. Yavuz, Robert J. Farrauto, Michael P. Galligan
Estimating the term…
Oxidation catalyst compositions include a catalytic material having a BET surface area of at least about 10 m.sup.2 /g and consisting essentially of a combination of bulk ceria and a bulk second metal oxide which may be one or more of titania, zirconia, ceria-zirconia, silica, alumina-silica and .alpha.-alumina. The combination may optionally also include activated alumina having a BET surface area of at least about 10 m.sup.2 /g. The ceria, second metal oxide and optional activated alumina may be mixed together or provided as discrete layers. Optionally, one of platinum or palladium metal may be dispersed on the catalytic material provided that the platinum, when used, is used in limited amounts to preclude excessive oxidation of SO.sub.2 to SO.sub.3. The catalyst compositions may be used for oxidation of oxidizeable components in a gas-borne stream, e.g., in a method to treat diesel engine exhaust by contacting the hot exhaust with the catalyst composition to promote the oxidation of the volatile organic fraction. The optional inclusion of platinum or palladium promotes the oxidation of gas phase components, e.g., hydrocarbons and carbon monoxide.
An oxidation catalyst composition comprises a refractory carrier on which is disposed a coating of a catalytic material having a BET surface area of at least about 10 m.sup.2 /g and consisting essentially of a combination of bulk ceria having a BET surface area of at least about 10 m.sup.2 /g and a bulk second metal oxide selected from the group consisting of one or more of titania, zirconia, ceria-zirconia, silica, alumina-silica, and .alpha.-alumina and from about 0.1 to 0.5 g/ft.sup.3 of platinum dispersed on the catalytic material.
A catalyst composition for purifying diesel engine exhaust comprising a refractory carrier on which is disposed a coating of a catalytic material having a BET surface area of at least 10 m.sup.2 /g and consisting essentially of a combination of bulk ceria having a BET surface area of at least about 10 m.sup.2 /g and a bulk second metal oxide selected from the class consisting of one or more of titania, zirconia, ceria-zirconia, silica, alumina-silica, and .alpha.-alumina, the ceria and the second metal oxide each comprising from about 5 to 95 percent by weight of the combination and from about 0.1 to 0.5 g/ft.sup.3 of platinum dispersed on the catalytic material.
Dependencies are inferred from the claim text.