Matte, heat-sealable, shrinkable, biaxially oriented, multilayer polypropylene film, process for the production thereof, and the use thereof
AssigneeHoechst Aktiengesellschaft
InventorsHerbert Peiffer, Ursula Murschall
Life of this patent
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Abstract
The invention relates to a heat-sealable, shrinkable multilayer polypropylene film which includes at least one base layer containing polypropylene or a polypropylene mixture and at least one outer layer which contains a mixture or a blend of two components I and II. The mixture contains copolymers and terpolymers of .alpha.-olefins having 2 to 10 carbon atoms and HDPE. The film has a longitudinal shrinkage of >8% at 120.degree. C. and .ltoreq.10% at 90.degree. C. The film has a transverse shrinkage of >10% at 120.degree. C. and .ltoreq.10% at 90.degree. C. The film has a minimum heat-sealing temperature of .ltoreq.124.degree. C. The film is matte.
Claims16
A heat-sealable, shrinkable multilayer polypropylene film having at least one matte surface, comprising:
- at least one base layer which comprises a propylene polymer or a propylene polymer mixture;
- and at least one outer layer which comprises a mixture or a blend of two components I and II, wherein
- component I is selected from the group consisting of
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- mixtures or blends thereof and
- a blend of two or more of said copolymers and terpolymers, mixed with one or more of said copolymers and terpolymers,
- and
- component II is selected from the group consisting of an HDPE and a blend of two components A and B, where
- blend component A is essentially an HDPE and
- blend component B is selected from the group consisting of
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms, and
- mixtures or blends thereof
- and wherein
- the multilayer film has, at 120.degree. C., a longitudinal shrinkage of greater than about 8%, and a transverse shrinkage of greater than 10%,
- the multilayer film has, at 90.degree. C. a longitudinal shrinkage of less than or equal to about 10%, and a transverse shrinkage of less than or equal to 10%, and the at least one outer layer has a minimum heat-sealing temperature of less than or equal to about 124.degree. C.
A heat-sealable, shrinkable multilayer polypropylene film having at least one matte surface, comprising:
- at least one base layer which comprises a propylene polymer or a propylene polymer mixture;
- and at least one outer layer which comprises a mixture or a blend of two components I and II, wherein
- component I is selected from the group consisting of
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- mixtures or blends thereof and
- a blend of two or more of said copolymers and terpolymers, mixed with one or more of said copolymers and terpolymers,
- and
- component II is selected from the group consisting of an HDPE and a blend of two components A and B, where
- blend component A is essentially an HDPE and
- blend component B is selected from the group consisting of
- a copolymer of ethylene and propylene,
- a copolymer of ethylene and butylene,
- a copolymer of propylene and butylene,
- a copolymer of ethylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a copolymer of propylene and another .alpha.-olefin having 5 to 10 carbon atoms,
- a terpolymer of ethylene and propylene and butylene,
- a terpolymer of ethylene and propylene and another .alpha.-olefin having 5 to 10 carbon atoms, and
- mixtures or blends thereof
- and wherein
- the multilayer film has, at 120.degree. C., a longitudinal shrinkage of greater than about 8%, and a transverse shrinkage of greater than 10%,
- the multilayer film has, at 90.degree. C., a longitudinal shrinkage of less than or equal to about 10%, and a transverse shrinkage of less than or equal to 10%, and
- the at least one outer layer has a minimum heat-sealing temperature of less than or equal to about 124.degree. C., and wherein said multilayer film is produced by a process comprising the steps of:
- coextruding the melts corresponding to the individual layers of the film through a flat-film die,
- taking the coextruded film off over a take-off roll whose temperature is between about 40 and 100.degree. C.,
- biaxially stretching the film at a longitudinal stretching ratio of about 4:1 to 9:1 and a transverse stretching ratio of about 6:1 to 10:1, heat-setting the biaxially stretched film and subsequently winding the film up.
Dependencies are inferred from the claim text.