US 5,489,419 AGranted

Process for pollution control

AssigneeNalco Fuel Tech

InventorsDaniel V. Diep, M. Linda Lin

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Abstract

Improved processes and improved compositions reduce the environmental damage caused by large-scale combustion, especially in the field of NO.sub.x reduction by selective noncatalytic reduction (SNCR) in the gas phase. In one aspect, the process improves the reliability of known means, compositions and methods for reducing the concentration of pollutants in a gas stream by: preparing an aqueous solution comprising a pollutant-reducing agent and a surface active agent in ratio of surface active agent to pollutant-reducing agent of greater than 1:4000, the amount and composition of surface active agent being effective to reduce average droplet size by at least 10%, and introducing the solution into the gas stream. Preferred surface active agents have HLB values of from about 8 to about 20, and are preferably anionic or nonionic agents such as C.sub.11 -C.sub.15 secondary alcohol ethoxylates, C.sub.12 -C.sub.15 linear primary alcohol ethoxylates, alkylated diphenyl oxide disulfonates and nonyl phenol ethoxylated ethanol.

Claims9

Dependent claims

A process for reducing the concentration of NO.sub.x in a combustion effluent by selective noncatalytic reduction in the gas phase, comprising:

diluting a concentration to prepare an aqueous solution of a NO.sub.x -reducing composition comprising from 1 to 25% of an NH-containing composition which comprises a member selected from the group consisting of ammonia, urea, carbamates, ammonium carbonate, ammonium bicarbonate, cyanurates, ammonium salts of organic acids, and mixtures thereof, the composition including a surface active agent in ratio of surface active agent in NH-containing composition of from 1:500 to 1:1250, the amount of surface active agent being effective to reduct average droplet size of said solution by at least 10% and the relative span of droplet sizes to less than 3;
and
dispersing said aqueous solution as droplets within the effulent at an effluent temperature of from 900.degree. to 1300.degree. C., wherein the average droplet size is within the range of from about 5 to 100 microns Sauter means diameter and the droplets are completely evaporated in under 1 second and prior to impingement on a surface within or defining a passage containing said combustion effluent to enable said gas phase reaction.

Dependencies are inferred from the claim text.