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US 5,480,629 AGranted
Catalytic production of hydrogen peroxide
AssigneeThe Trustees of Princeton University
InventorsMark E. Thompson, Jonathan L. Snover, Vijay Joshi, Lori A. Vermeulen
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Abstract
A method for the production of hydrogen peroxide from a source of hydrogen and a source of oxygen in the presence of a catalyst comprising the formula: (Y.sup.1 O.sub.3 --Z--Y.sup.2 O.sub.3)(Y.sup.3 O.sub.3 R.sup.3)Me Y.sup.1, Y.sup.2 and Y.sup.3 being phosphorus or arsenic; Z being a divalent group containing two conjugated cationic centers; R.sup.3 being a capping group and Me being a trivalent or tetravalent metal.
Claims20
A catalytic process for producing hydrogen peroxide from oxygen and hydrogen comprising the steps of:
- A) treating an aqueous suspension of heterogeneous catalyst with a source of oxygen and a source of hydrogen;
- B) separating the catalyst;
- and,
- C) isolating the produced hydrogen peroxide,
- wherein said catalyst is a complex of the formula:
- [[(Y.sup.1 O.sub.3 --Z--Y.sup.2 O.sub.3).multidot.p(X.sup.2/p-)].sub.1-n (Y.sup.3 O.sub.3 R.sup.3).sub.2n Me.sup.2 ]*Pt*Pd
- wherein
- each of Y.sup.1, Y.sup.2, and Y.sup.3, independently of the other, is phosphorus or arsenic;
- Z is a divalent group which reversibly forms a stable reduced form, said group containing two conjugated cationic centers which together have a negative E.degree..sub.red value;
- Me.sup.2 is a trivalent or tetravalent metal of Group III, IVA, or IVB having an atomic number of at least 21 or a lanthanide;
- X is anion;
- n has a value of from 0 to 0.8;
- and
- p has a value of 1, 2 or 3;
- and
- R.sup.3 is a nonreducible capping group.
13 more elements
Dependencies are inferred from the claim text.