Aspartic acid copolymers and their preparation
AssigneeDonlar Corporation
InventorsLarry P. Koskan, James F. Kneller, Daniel A. Batzel
Life of this patent
Estimating the term…
Abstract
Aspartic acid precursors such as mono and diammonium maleate, maleamic acid, ammonium maleamate, ammonium malate and mixtures of these and other precursors are copolycondensed thermally with a variety of mono, di and multifunctional monomers containing amino, hydroxyl and carboxyl functional groups. The resulting condensation copolymers and terpolymers contain succinimide units derived from aspartic acid precursors, condensed with other functional group monomers usually though amide and ester linkages. Hydrolysis of the polysuccinimide copolymers and terpolymers with alkali, alkaline earth and ammonium hydroxide produces aspartic acid copolymer and terpolymer salts.
Claims5
A method for producing aspartic acid copolymers and salts which comprises heating mixtures of aspartic acid precursors and substituted aspartic acid precursors with amino, hydroxyl, and substituted aspartic acid precursors with amino, hydroxyl, and carboxyl functional group containing monomers at a temperature of at least 120.degree. C. a sufficient length of time for thermal polymerization to a polysuccinimide copolymer to occur and subsequently hydrolyzing the polysuccinimide copolymer with alkali, alkaline earth, or ammonium hydroxides, to form the aspartic acid copolymer and salts, wherein the said mixture of aspartic acid precursors and substituted aspartic acid precursors comprise at least one of the following combinations of compounds:
- maleic anhydride and ammonium carbonate, citraconic anhydride and ammonium carbonate, itaconic anhydride and ammonium carbonate, maleic anhydride and asparagine, citraconic anhydride and asparagine, iraconic anhydride and asparagine, maleic anhydride and ammonium maleamate, citraconic anhydride and ammonium maleamate, itaconic anhydride and ammonium maleamate, maleic anhydride and monoammonium aspartate, itaconic anhydride and monoammonium aspartate, maleic acid and ammonium carbonate, citraconic acid and ammonium carbonate, itaconic acid and ammonium carbonate, maleic acid and asparagine, citraconic acid and asparagine, itaconic acid and asparagine, maleic acid and ammonium maleamate, citraconic acid and ammonium maleamate, iraconic acid and ammonium maleamate, maleic acid and monoammonium aspartate, citraconic acid and monoamonium aspartate, itaconic acid and monoammonium aspartate, malic acid and ammonium carbonate, malic acid and asparagine, malic acid and ammonium maleamate, malic acid and monoammonium aspartate, fumaric acid and ammonium carbonate, fumaric acid and asparagine, fumaric acid and ammonium maleamate, fumaric acid and monoammonium aspartate, maleic anhydride and mono and diammonium maleate, citraconic anhydride and mono and diammonium maleate, iraconic anhydride and mono and diammonium maleamate, maleic acid and mono and diammonium maleamate, malic acid and mono and diammonium maleamate, iraconic acid and mono and diammonium maleate, citraconic acid and mono and diammonium maleate.
Dependencies are inferred from the claim text.