Photographic elements containing development accelerators and release compounds that release development inhibitors
AssigneeEastman Kodak Company
InventorsKeath T. Chen, John V. Nelson, David A. Dickinson, Thomas R. Welter
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Abstract
A photographic element comprising a support having located thereon at least one silver halide emulsion layer, the emulsion layer containing a development accelerator and a release compound that provides a non-imagewise distribution of a development inhibitor moiety. The release compound is characterized in that it comprises a blocking group from which the development inhibitor moiety is released.
Claims15
A silver halide color reversal, black and white, or color negative photographic element comprising a support having located thereon at least one silver halide emulsion layer, the emulsion layer containing a development accelerator and release compound that provides a non-imagewise distribution of a development inhibitor moiety, the release compound comprising a blocking group from which the development inhibitor moiety is released, a ballasting group other than a coupler moiety, and an aqueous solubilizing group, both the ballasting group and the aqueous solubilizing group being attached to the blocking group, and not directly to the development inhibitor moiety, wherein:
- (a) the blocking group comprises an aromatic ring system which is unsubstituted or substituted with one or more electron withdrawing groups and, optionally, a timing group or series of timing groups from which the development inhibitor moiety is released;
- (b) the aqueous solubilizing group is attached, either directly or indirectly, to a timing group, or is attached indirectly through at least one carbon atom to the aromatic ring system;
- and
- (c) the active functionality of the development inhibitor moiety is a heteroatom which is blocked by direct attachment to a timing group or aromatic ring of the aromatic ring system.
A photographic element according to claim 6 wherein the release compound is selected from ##STR73## wherein R.sup.1, m, n, TIME and INH are as defined in claim 8;
- R.sup.2 is a group containing a ballasting group;
- o is 1 or 2;
- R.sup.3 is a group containing an aqueous solubilizing group;
- p is 1 or 2;
- R.sup.4 is a group containing both a ballasting group and an aqueous solubilizing group, wherein the aqueous solubilizing group is attached to the six-membered carbocyclic ring through at least one carbon atom;
- and
- q is 1 or 2.
A photographic element according to claim 10 wherein the release compound is ##STR77## wherein INH is as described in claim 13.
A silver halide color reversal, black and white, or color negative photographic element comprising a support having located thereon at least one silver halide emulsion layer, the emulsion layer containing a development accelerator and release compound that provides a non-imagewise distribution of a development inhibitor moiety, the release compound comprising a blocking group comprising a carbocyclic ring and, optionally, a timing group or series of timing groups from which the development inhibitor moiety is released, and the development inhibitor moiety comprising as its active functionality a heteroatom which is blocked by direct attachment to a timing group or the carbocyclic ring.
Dependencies are inferred from the claim text.