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US 5,476,974 AGranted
Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application
AssigneeMinnesota Mining and Manufacturing Company
InventorsGeorge G. I. Moore, Miguel A. Guerra
Life of this patent
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Abstract
Normally liquid, omega-hydrofluoroalkyl ether compounds (and selected mixtures thereof) have a saturated perfluoroaliphatic chain of carbon atoms interrupted by one or more ether oxygen atoms. The compounds can be prepared, e.g., by decarboxylation of the corresponding fluoroalkyl ether carboxylic acids and are useful, e.g., in cleaning and drying applications.
Claims3
A compound represented by the formula:
- R.sub.fs --O--(CF.sub.2).sub.b --Z
- where
- R.sub.fs is a linear or branched perfluoroalkyl group having from 1 to 18 carbon atoms;
- "b" is an integer of at least 3;
- and
- Z is selected from the group consisting of --COOH, --COOM.sub.1/v, --COONH.sub.4, --COOR, --CH.sub.2 OH, --COF, --COCl, --COR, --CONRR, --CH.sub.2 NH.sub.2, --CH.sub.2 NCO, --CN, --CH.sub.2 OSO.sub.2 R, --CH.sub.2 OCOR, --CH.sub.2 OCOCR.dbd.CH.sub.2, --CONH(CH.sub.2).sub.m Si(OR).sub.3, and --CH.sub.2 O(CH.sub.2).sub.m Si(OR).sub.3, where M is an ammonium radical or a metal atom having a valence "v" of 1 to 4, each R is independently selected from the group consisting of alkyl groups having from 1 to 14 carbon atoms, fluoroalkyl groups having from 1 to 14 carbon atoms, aryl groups having from 6 to 10 ring-carbon atoms, and heteroatom-containing alkyl groups having from 1 to 14 carbon atoms, fluoroalkyl groups having from 1 to 14 carbon atoms, and aryl groups having from 6 to 10 ring-carbon atoms, and m is an integer of 1 to 11.
3 more elements
A compound represented by the formula:
- R.sub.ft --(O--R.sub.ft ')c--O--(CF.sub.2)d--Z
- wherein:
- R.sub.ft is a linear or branched perfluoroalkyl group having from 1 to 18 carbon atoms;
- R.sub.ft ' is a linear or branched perfluoroalkylene group having from 1 to 11 carbon atoms;
- c is an integer of at least 1;
- d is an integer of at least 3;
- and
- Z is selected from the group consisting of --COOH, --COOM.sub.1/v, --COONH.sub.4, --COOR, --CH.sub.2 OH, --COF, --COCl, --COR, --CONRR, --CH.sub.2 NH.sub.2, --CH.sub.2 NCO, --CN, --CH.sub.2 OSO.sub.2 R, --CH.sub.2 OCOR, --CH.sub.2 OCOCR=CH.sub.2, --CONH (CH.sub.2).sub.m Si(OR).sub.3, and --CH.sub.2 O(CH.sub.2).sub.m Si(OR).sub.3, where M is an ammonium radical or a metal atom having a valence "v" of 1 to 4, each R is independently selected from the group consisting of alkyl groups having from 1 to 14 carbon atoms, fluoroalkyl groups having from 1 to 14 carbon atoms, aryl groups having from 6 to 10 ring-carbon atoms, and heteroatom-containing alkyl groups having from 1 to 4 carbon atoms, fluoroalkyl groups having from 1 to 14 carbon atoms, and aryl groups having from 6 to 10 ring-carbon atoms, and m is an integer of 1 to 11.
5 more elements
Dependencies are inferred from the claim text.