A plastic optical waveguide, which comprises a plastic optical waveguide whose core layer comprises an aromatic poycarbonate copolymer that is obtained by reacting a dihydric phenol component, comprising 53 to 99.5 mol % of (A) 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 47 to 0.5 mol % of (B) 9,9-bis(4-hydroxyphenyl)fluorene, with a carbonate precursor substance;
- wherein when 0.7 g of said aromatic polycarbonate copolymer is dissolved in 100 ml of methylene chloride, the specific viscosity of the thus obtained solution measured at 20.degree. C. is in the range of 0.160 to 0.418.