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AssigneeUop LLC
InventorsTimothy A. Brandvold, Jennifer S. Holmgren, Thomas P. Malloy
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A process of effecting an acid catalyzed reaction wherein a reactant capable of undergoing an acid catalyzed reaction is contacted with an acid functionalized organically-bridged polysilsesquioxane catalyst where all of the acid functionality is covalently bonded to the organic portion of an organically-bridged polysilsesquioxane framework has been developed. The acid functionalized organically-bridged polysilsesquioxane is formed by polymerizing a monomer through sol-gel processing to form an organically-bridged polysilsesquioxane, reacting an acid group onto the organic portion of the organically-bridged polysilsesquioxane, and recovering the acid functionalized product. An embodiment of the invention is where the acid catalyzed reaction is the hydration of olefins, alkylation, acylation, isomerization, or aldol condensation/elimination. A specific embodiment of the invention is effecting the aldol condensation/elimination reaction of acetone with itself to form mesityl oxide by contacting the acetone with an effective amount of sulfonated phenylene-bridged polysilsesquioxane.
A process for conducting an acid catalyzed reaction comprising contacting reactants capable of undergoing an acid catalyzed reaction with an amount effective to catalyze an acid catalyzed reaction of an acid functionalized organically-bridged polysilsesquioxane whose repeating unit is ##STR6## where X is a divalent organic group selected from the group consisting of naphthylene, anthrylene, phenylene, biphenylene, terphenylene, and divalent aromatic radicals whose parents are selected from the group consisting of benzophenone, diphenylmethane, diphenylamine and diphenylsulfone, where at least about 0.2 percent of which is covalently bonded to a sulfuric acid group.
Dependencies are inferred from the claim text.