Arthropodicidal pyrazolines, pyrazolidines and hydrazines
AssigneeE. I. Du Pont de Nemours and Company
InventorsCharles R. Harrison, Renee M. Lett, Stephen F. McCann, Rafael Shapiro, Thomas M. Stevenson
Life of this patent
Estimating the term…
Abstract
Arthropodicidal pyrazoline, pyrazolidine and hydrazine compounds, including all their geometric and stereoisomers, agriculturally suitable salts thereof and compositions containing them; and a method for controlling arthropods employing said compounds which are: ##STR1## wherein Q, X, X.sup.1, Y and G are as defined in the text.
Claims8
A compound selected from ##STR67## wherein Q is selected from the group ##STR68## A is selected from the group CH.sub.2 and CH.sub.2 CH.sub.2, each optionally substituted with substituents independently selected from 1 to 2 halogen and methyl;
- G is selected from the group ##STR69## X is selected from the group O and S;
- X.sup.1 is selected from the groups Cl, Br, OR.sup.6, SR.sup.6 and N(R.sup.6) R.sup.7 ;
- Y is H;
- R.sup.1 and R.sup.2 are independently selected from the group H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 haloalkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.2 -C.sub.6 alkoxyalkyl, C.sub.2 -C.sub.6 alkylthioalkyl, C.sub.1 -C.sub.6 nitroalkyl, C.sub.2 -C.sub.6 cyanoalkyl, C.sub.3 -C.sub.8 alkoxycarbonylalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 halocycloalkyl, halogen, CN, N.sub.3, SCN, NO.sub.2, OR.sup.15, SR.sup.15, S(O)R.sup.15, S(O).sub.2 R.sup.15, OC(O)R.sup.15, OS(O).sub.2 R.sup.15, CO.sub.2 R.sup.15, C(O)R.sup.15, C(O)N(R.sup.15)R.sup.16, SO.sub.2 N(R.sup.15)R.sup.16, N(R.sup.15)R.sup.16, N(R.sup.16)C(O)R.sup.15, OC(O)NHR.sup.15, N(R.sup.16)C(O)NHR.sup.15, N(R.sup.16)SO.sub.2 R.sup.15, phenyl optionally substituted with 1 to 3 substituents independently selected from W and benzyl optionally substituted with 1 to 3 substituents independently selected from W;
- or when m, n or p is 2, (R.sup.1).sub.2 can be taken together, or (R.sup.2).sub.2 can be taken together or (R.sup.14).sub.2 can be taken together as -6OCH.sub.2 O, --OCF.sub.2 O, OCH.sub.2 CH.sub.2 O, CF.sub.2 CF.sub.2 O, --CH.sub.2 C(CH.sub.3).sub.2 O-- or --OCF.sub.2 CF.sub.2 O-- to form a cyclic bridge between adjacent atoms on the same ring;
- R.sup.3 is selected from the group consisting of pyrrolyl, pyrazolyl, imidazolyl, pyridyl, pyrazinyl, pyrimidinyl, and pyridazinyl, containing one carbonyl and optionally containing one substituent group selected from W;
- Z is (CH.sub.2).sub.q where q is 2-4, wherein said group is optionally substituted with 1-2 CH.sub.3 ;
- R.sup.18 is selected from the group H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkylcarbonyl, C.sub.2 -C.sub.4 haloalkylcarbonyl, C.sub.2 -C.sub.4 alkoxycarbonyl, C.sub.2 -C.sub.4 haloalkoxycarbonyl, C.sub.2 -C.sub.5 alkylaminocarbonyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 halocycloalkyl, C.sub.4 -C.sub.7 alkylcycloalkyl, C.sub.4 -C.sub.7 haloalkylcycloalkyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfonyl and SO.sub.2 Ph optionally substituted with Cl, Br or CH.sub.3 ;
- R.sup.19 is selected from the group H, C.sub.1 -C.sub.3 alkyl, CO.sub.2 R.sup.18, phenyl and phenyl substituted with W;
- R.sup.6 is selected from the group C.sub.1 -C.sub.3 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.2 -C.sub.4 haloalkenyl, C.sub.3 -C.sub.6 cycloalkyl and C.sub.1 -C.sub.3 alkyl substituted with OCH.sub.3, OCH.sub.2 CH.sub.3, NO.sub.2, CN, CO.sub.2 CH.sub.3, CO.sub.2 CH.sub.2 CH.sub.3, SCH.sub.3 or SCH.sub.2 CH.sub.3 ;
- benzyl optionally substituted with the group halogen, CN, C.sub.1 -C.sub.3 haloalkyl and C.sub.1 -C.sub.3 haloalkoxy;
- R.sup.7 is selected from the group H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkoxycarbonyl, optionally substituted phenyl and optionally substituted pyridinyl wherein the substituent(s) are selected from the group halogen, CN, C.sub.1 -C.sub.3 haloalkyl and C.sub.1 -C.sub.3 haloalkoxy;
- R.sup.15 is selected from the group H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 haloalkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.2 -C.sub.6 alkoxyalkyl, C.sub.2 -C.sub.6 alkylthioalkyl, C.sub.1 -C.sub.6 nitroalkyl, C.sub.2 -C.sub.6 cyanoalkyl, C.sub.3 -C.sub.8 alkoxycarbonylalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 halocycloalkyl, optionally substituted phenyl and optionally substituted benzyl wherein the substituent(s) are 1 to 3 substituents independently selected from W;
- R.sup.16 is selected from H and C.sub.1 -C.sub.4 alkyl;
- W is selected from the group halogen, CN, NO.sub.2, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 haloalkoxy, C.sub.1 -C.sub.2 alkylthio, C.sub.1 -C.sub.2 haloalkylthio, C.sub.1 -C.sub.2 alkylsulfonyl and C.sub.1 -C.sub.2 haloalkylsulfonyl;
- m is 1 to 3;
- n is 1 to 3;
- and
- u is 1 or 2.
Dependencies are inferred from the claim text.