Back to results
US 5,473,068 AGranted
Photochromic spirooxazine monomers and polysiloxanes
AssigneeYeda Research and Development Co. Ltd. at the Weizmann Institute of Science
InventorsValeri Krongauz, Frida Buchhultz, Alexander Zelichenok, Shlomo Yitzchaik
Life of this patent
Estimating the term…
Abstract
A method of making a photochromic polysiloxane includes the steps of forming a photochromic spironaphthooxazine monomer including an alkene terminated side and, by addition reaction, covalently bonding the alkene carbon to [SiH] moieties of a siloxane polymer. Novel spironaphthooxazine monomers and photochromic polysiloxanes are disclosed.
Claims6
A photochromic compound of the formula:
- ##STR9## wherein R.sup.1 is selected from the group consisting of (A) hydrogen, alkyl, phenyl, benzyl, or an alkyl substituted by halogen, hydroxy, lower alkoxy, carboxyl, lower alkoxycarbonyl, and phenyl and benzyl substituted by cyano or by one or more halogens;
- and (B) (CH.sub.2).sub.n --CH.dbd.CH.sub.2 wherein n is an integer from 1 to 20;
- when R.sup.1 is (B), then R.sup.2 through R.sup.8 are each selected from the group consisting of hydrogen, lower alkyl, and lower alkyl including substitutions from the group consisting of halogen, hydroxy, and lower alkoxy;
- when R.sup.1 is (A) then one of R.sup.2 through R.sup.8 is (C) --X--(CH.sub.2).sub.n --CH.dbd.CH.sub.2, wherein n is an integer from 4 to 20 and X is selected from the group consisting of a covalent bond, O, N--R', (wherein R' is H or lower alkyl), CO--O, CO--NH, and --CH.dbd.N and the remaining ones of R.sup.2 through R.sup.8 are selected from the group consisting of hydrogen, alkyl, and alkyl substituted by halogen, hydroxy and lower alkoxy;
- and R.sup.9 and R.sup.10 form a condensed benzene or pyridine ring.
2 more elements
Dependencies are inferred from the claim text.