Herbicidal pyrrolesulfonylureas

A compound of the formula ##STR67## wherein:

• J is ##STR68## W is O or S;
• R is H or CH.sub.3 ;
• R.sup.1 is H;
• CH.sub.3 ;
• CH.sub.2 OCH.sub.3 ;
• CH.sub.2 OC.sub.2 H.sub.5 ;
• CH.sub.2 CN;
• CH.sub.2 SCH.sub.3, CH.sub.2 SC.sub.2 H.sub.5 ;
• C.sub.2 -C.sub.6 alkyl optionally substituted with one C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, CN or one or more halogens;
• C.sub.3 -C.sub.4 alkenyl;
• C.sub.3 -C.sub.4 haloalkenyl;
• C.sub.3 -C.sub.6 cycloalkyl;
• C(O)R.sup.5 ;
• N(CH.sub.3).sub.2 ;
• or Q.sup.1 ;
• R.sup.2 is C.sub.1 -C.sub.4 alkyl optionally substituted with one CN, C.sub.2 -C.sub.3 alkylcarbonyl, methoxycarbonyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, C.sub.1 -C.sub.2 alkylsulfonyl, S(O).sub.2 NR.sup.6 R.sup.7, OH or one or more halogens;
• C.sub.2 -C.sub.4 alkenyl optionally substituted with one C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, CN or one or more halogens;
• CN;
• C(O)R.sup.8 ;
• C(O)OR.sup.9 ;
• C(O)NR.sup.10 R.sup.11 ;
• C(R.sup.12).dbd.NOR.sup.13 ;
• C(R.sup.14)(OR.sup.15)(OR.sup.16);
• S(O).sub.n R.sup.17 ;
• S(O).sub.2 NR.sup.18 R.sup.19 ;
• NO.sub.2 ;
• halogen;
• or OR.sup.73 ;
• R.sup.3 is H, halogen or C.sub.1 -C.sub.4 alkyl;
• R.sup.4 is H, C.sub.1 -C.sub.4 alkyl optionally substituted with one CN, C.sub.2 -C.sub.3 alkylcarbonyl, methoxycarbonyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, C.sub.1 -C.sub.2 alkylsulfonyl, S(O).sub.2 NR.sup.6 R.sup.7, OH or one or more halogens;
• C.sub.2 -C.sub.4 alkenyl optionally substituted with one C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, CN or one or more halogens;
• CN;
• C(O)R.sup.8 ;
• C(O)OR.sup.9 ;
• C(O)NR.sup.10 R.sup.11 ;
• C(R.sup.12).dbd.NOR.sup.13 ;
• S(O).sub.n R.sup.17 ;
• S(O).sub.2 NR.sup.18 R.sup.19 ;
• or halogen;
• R.sup.5 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or NR.sup.20 R.sup.21 ;
• R.sup.6 is H, C.sub.1 -C.sub.2 alkyl or OCH.sub.3 ;
• R.sup.7 is C.sub.1 -C.sub.2 alkyl;
• or
• R.sup.6 and R.sup.7 can be taken together as --(CH.sub.2).sub.3 -- or --(CH.sub.2).sub.4 --;
• R.sup.8 is H, C.sub.1 -C.sub.3 alkyl or cyclopropyl;
• R.sup.9 is CH.sub.3 ;
• C.sub.2 -C.sub.3 alkyl optionally substituted with one C.sub.1 -C.sub.2 alkoxy, OH, CN or one or more halogens;
• C.sub.3 -C.sub.4 alkenyl;
• or propargyl;
• R.sup.10 is H, C.sub.1 -C.sub.3 alkyl or OCH.sub.3 ;
• R.sup.11 is C.sub.1 -C.sub.3 alkyl;
• or
• R.sup.10 and R.sup.11 can be taken together as --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 -- or --(CH.sub.2).sub.2 O(CH.sub.2).sub.2 --;
• R.sup.12 is H, C.sub.1 -C.sub.3 alkyl, allyl, halogen, CN, N.sub.3, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio or SCN;
• R.sup.13 is C.sub.1 -C.sub.3 alkyl or allyl;
• R.sup.14 is H or C.sub.1 -C.sub.3 alkyl;
• R.sup.15 and R.sup.16 are independently C.sub.1 -C.sub.2 alkyl;
• R.sup.17 is C.sub.1 -C.sub.4 alkyl, optionally substituted with one C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.2 alkylthio, CN or one or more halogens;
• C.sub.3 -C.sub.4 alkenyl;
• or cyclopropylmethyl;
• R.sup.18 is H, C.sub.1 -C.sub.3 alkyl or OCH.sub.3 ;
• R.sup.19 is H or C.sub.1 -C.sub.2 alkyl;
• or
• R.sup.18 and R.sup.19 can be taken together as --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 -- or --(CH.sub.2).sub.5 --;
• R.sup.20 and R.sup.21 are independently C.sub.1 -C.sub.2 alkyl;
• or
• R.sup.20 and R.sup.21 can be taken together as --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 -- or --(CH.sub.2).sub.2 O(CH.sub.2).sub.2 --;
• R.sup.71 is H, halogen or CF.sub.3 ;
• R.sup.73 is C.sub.1 -C.sub.4 alkyl optionally substituted with one or more halogens, CN, C.sub.1 -C.sub.2 alkoxy, or C.sub.1 -C.sub.2 alkylthio;
• C(O)R.sup.74 ;
• SO.sub.2 R.sup.75 ;
• C.sub.3 -C.sub.4 alkenyl;
• or propargyl;
• R.sup.74 is C.sub.1 -C.sub.4 alkyl optionally substituted with C.sub.1 -C.sub.2 alkoxy, one or more halogens, or CN;
• C.sub.3 -C.sub.4 alkenyl;
• or C.sub.1 -C.sub.3 alkoxy;
• R.sup.75 is C.sub.1 -C.sub.3 alkyl or CF.sub.3 ;
• n is 0, 1 or 2;
• Q.sup.1 is ##STR69## A is ##STR70## X is H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy, amino, C.sub.1 -C.sub.3 alkylamino or di(C.sub.1 -C.sub.3 alkyl)amino;
• Y is H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy, amino, C.sub.1 -C.sub.3 alkylamino, di(C.sub.1 -C.sub.3 alkyl)amino, C.sub.3 -C.sub.4 alkenyloxy, C.sub.3 -C.sub.4 alkynyloxy, C.sub.2 -C.sub.5 alkylthioalkyl, C.sub.2 -C.sub.5 alkylsulfinylalkyl, C.sub.2 -C.sub.5 alkylsulfonylalkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkynyl, C.sub.3 -C.sub.5 cycloalkyl, azido, cyano, ##STR71## or N(OCH.sub.3)CH.sub.3 ;
• p is 2 or 3;
• Q.sup.3 and Q.sup.4 are independently O or S;
• R.sup.22 is H or C.sub.1 -C.sub.3 alkyl;
• R.sup.23 and R.sup.24 are independently C.sub.1 -C.sub.3 alkyl;
• Z is N;
• and
• X.sup.3 is CH.sub.3 or OCH.sub.3 ;
• q is 0 or 1;
• R.sup.25 and R.sup.26 are independently H, CH.sub.3 or Cl;
• R.sup.27 and R.sup.28 are independently H, F, or CH.sub.3 ;
• R.sup.29 is H, CH.sub.3 or OCH.sub.3 ;
• R.sup.30 is H or CH.sub.3 ;
• R.sup.31, R.sup.32 and R.sup.33 are independently H, CH.sub.3 or OCH.sub.3 ;
• R.sup.34, R.sup.35 and R.sup.36 are independently H, CH.sub.3, CH.sub.2 CH.sub.3, Cl, Br, OCH.sub.3 or OCH.sub.2 CH.sub.3 ;
• R.sup.37 is H or C.sub.1 -C.sub.2 alkyl;
• R.sup.38 is CH.sub.3 ;
• R.sup.39 is H, C.sub.1 -C.sub.2 alkyl, OCH.sub.3 or SCH.sub.3 ;
• R.sup.40 is H, CH.sub.3 or CH.sub.2 CH.sub.3 ;
• R.sup.41 and R.sup.42 are independently H, or CH.sub.3 ;
• R.sup.43 is H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.3 H.sub.7 ;
• W.sup.1 is O or S;
• W.sup.2 is O, S or NR.sup.44 ;
• R.sup.44 is H or CH.sub.3 ;
• and their agriculturally suitable salts;
• provided that:
• (a) when W is S, then R is H, A is A-1 and Y is CH.sub.3, OCH.sub.3, OCH.sub.2 CH.sub.3, CH.sub.2 OCH.sub.3, CH.sub.2 CH.sub.3, CF.sub.3, SCH.sub.3, OCH.sub.2 CH.dbd.CH.sub.2, OCH.sub.2 C.tbd.CH, OCH.sub.2 CH.sub.2 OCH.sub.3, CH(OCH.sub.3).sub.2 or ##STR72## (b) when the total number of carbon atoms of X and Y is greater than four, then the number of carbons of Q.sup.1 is less than or equal to eight;
• (c) when A is A-6 then R is H;
• (d) when J is J-1, A is A-1 and X and/or Y is alkyl, then R.sup.2 is other than CN or NO.sub.2.