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US 5,472,741 AGranted
Softening and waterproofing retanning agents
AssigneeBayer Aktiengesellschaft
InventorsGunter Sackmann, Bruno Bomer, Joachim Kochta, Henricus Slaats
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Abstract
Copolymers containing incorporated radicals of long-chain alcohols and neutralized carboxyl groups are suitable as retanning agents for leather. They result in an excellent combination of water repellency, softness and grain tightness.
Claims3
In the retanning of leather wherein the leather is contacted with a retanning agent, the improvement which comprises employing as said retanning agent the reaction product of
- (A) a terpolymer having molecular weights M.sub.n, determined as number average, of 5000 to 60 000 comprised of
- a) maleic anhydride,
- b) 80 to 120 mol %, relative to component a), of diisobutylene, and
- c) 1 to 12 mol % relative to component a), of at least one monomer of the formula ##STR3## in which R.sup.1 denotes hydrogen or methyl,
- R.sup.2 denotes hydrogen, methyl, ethyl, --OR.sup.3, ##STR4## unsubstituted or C.sub.1 -C.sub.4 -alkyl substituted phenyl or hydroxymethyl, and
- R.sup.3 denotes C.sub.1 -C.sub.4 -alkyl,
- (B) an aliphatic and/or cycloaliphatic monohydric C.sub.6 -C.sub.24 -alcohol, and
- (C) a base,
- wherein 20 to 80% of the carboxyl groups corresponding to the anhydride groups of the terpolymer are esterified with alcohol (B) and at least 20% of the remaining carboxyl groups are neutralized with base (C).
6 more elements
Dependencies are inferred from the claim text.