Thermal recording sheet
AssigneeNippon Paper Industries Co., Ltd.
InventorsToshimi Satake, Toshiyuki Takano, Hideki Hayasaka, Yukiko Uehori, Tomoaki Nagai
Life of this patent
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Abstract
In a thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor upon heating to develop a color, a dimerized or trimerized urea compound is used as the color developer to obtain a thermal recording sheet which is superior in ground color stability and a thermal recording sheet having a reversible recordability.
Claims15
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound having at least two groups of Formula (1) in the molecule, and the thermal recording layer contains at least one of said urea compound:
- ##STR14## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group or hydrogen group.
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound of Formula (2), (3), or (4), and the thermal recording layer contains at least one of said urea compounds:
- ##STR15## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group, or hydrogen group, A denotes a divalent group comprising 30 or less carbon atoms, and B denotes a trivalent group comprising 30 or less carbon atoms, n is an integer from 1 to 3.
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound of Formula (5), and the thermal recording layer contains at least one of said urea compound:
- ##STR16## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group, or hydrogen group, n is an integer from 1 to 3, and m is an integer from 1 to 12.
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound of Formula (2), and the thermal recording layer contains at least one of said urea compound:
- ##STR17## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group, or hydrogen group.
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound of Formula (3), and the thermal recording layer contains at least one of said urea compound:
- ##STR18## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group, or hydrogen group, A denotes a divalent group comprising 30 or less carbon atoms, and n is an integer from 1 to 3.
A thermal recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with said dye precursor upon heating to develop a color, wherein said color developer is a urea compound of Formula (4), and the thermal recording layer contains at least one of said urea compound:
- ##STR19## wherein X is alkyl group having 1 to 12 carbon atoms, halogenated alkyl group having 1 to 6 carbon atoms, aralkyl group having 7 to 14 carbon atoms, alkoxy group having 1 to 12 carbon atoms, aryloxy group having 6 to 12 carbon atoms, alkoxycarbonyl group having 1 to 12 carbon atoms, acyl group having 1 to 12 carbon atoms, dialkylamino group having 1 to 12 carbon atoms, arylalkylamino group having 7 to 12 carbon atoms, arylamino group having 6 to 12 carbon atoms, acylamino group having 1 to 12 carbon atoms, nitro group, cyano group, halogen group, or hydrogen group, B denotes a trivalent group comprising 30 or less carbon atoms, and n is an integer from 1 to 3.
Dependencies are inferred from the claim text.