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US 5,470,356 AGranted
Sulfur dye compositions and their production
OwnerLaszlo A. Meszarosinventor
Life of this patent
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Abstract
A sulfur dye or sulfurized vat dye is treated in an aqueous reducing medium, preferably an aqueous mixture of alkali and reducing sugar, to form a solution which is then oxidized to form particles of the dye having improved characteristics.
Claims31
A process for producing a dye slurry which comprises the steps of
- 1) reducing a starting sulfur dye, which contains disulfide groups, in an amount of a non-sulfide reducing agent-containing aqueous reducing medium which is effective to reduce said disulfide groups and dissolve any solid particles of the dye and produce an aqueous solution of the reduced form of the dye which can be oxidized to form an aqueous slurry of precipitated solid particles of the dye which differ from particles obtainable by oxygenating an aqueous composition of the starting dye by virtue of a) being softer, b) being of more uniform particle size, c) being of smaller average particle size, d) containing less bound sulfur, e) containing less free sulfur or f) any combination of a)-e), and
- 2) oxidizing the solution obtained in step 1) to produce said slurry of precipitated solid particles of the dye.
A process for producing an aqueous dye slurry which comprises the steps of
- 1) heating crude C.I. Sulfur Black 1 dye in an aqueous alkaline medium containing a reducing sugar for a sufficient time to dissolve all of the solid material in the crude dye and reduce bound and free sulfur contained therein, and
- 2) oxygenating the resulting solution for a sufficient time to produce a slurry of precipitated solid particles of the dye.
Dependencies are inferred from the claim text.