In a method of cleaning a reflector mirror in an optical dew point meter that measures the dew point or frost point of a sample gas by a process including the steps of bringing the sample gas into contact with the reflector mirror whose temperature is variable, projecting condensed rays of light or laser light onto said reflector mirror, and detecting the change in the intensity of scattered light or reflected light on account of the dew or frost formed on said reflector mirror, characterized in that the cleaning steps of said method comprise the step of bringing CO.sub.2 gas of five-nine grade purity, CO.sub.2 gas or CO.sub.2 containing gas, said CO.sub.2 gas or CO.sub.2 containing gas having been purified for removal of water, oils and particles, into contact with the reflector while the latter is in a cooled state, thereby condensing CO.sub.2 on the surface of the reflector mirror, and the subsequent step of heating the reflector mirror to vaporize the CO.sub.2.