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US 5,468,848 AGranted
Basic azo dyestuffs of the 3-cyano-2,4,6-triamino pyridine series
AssigneeBayer Aktiengesellschaft
InventorsKarin Hassenruck, Peter Wild
Life of this patent
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Abstract
The new basic azo dyestuffs of the formula ##STR1## wherein the symbols have the meaning given in the description, are suitable for dyeing synthetic and naturally occurring substrates which can be dyed with basic dyestuffs.
Claims6
An azo dyestuff of the formula ##STR40## wherein R.sup.1 represents hydrogen, alkyl or aryl or
- R.sup.1 and R.sup.2, together with B and the two nitrogen atoms to which they are bonded, form an optionally substituted 5- or 6-membered heterocyclic ring, and in this-case B represents a direct bond, --CH.sub.2 -- or --CH.sub.2 CH.sub.2 --,
- R.sup.2 and R.sup.3 independently of one another represent hydrogen, alkyl, alkenyl or aralkyl or
- R.sup.2 and R.sup.3, together with the nitrogen atom to which they are bonded, form an optionally substituted 5- or 6-membered heterocyclic ring,
- n represents 2 and
- D represents the radical of a tetrazo component of the formula ##STR41## wherein R.sup.7 -R.sup.10 independently of one another represent hydrogen, SO.sub.3 H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine,
- B represents C.sub.2 -C.sub.5 -alkylene which is optionally interrupted by ##STR42## wherein R represents hydrogen, or represents C.sub.1 -C.sub.4 -alkyl which is optionally substituted by chlorine, bromine, hydroxyl, cyano, C.sub.1 -C.sub.4 -alkoxy, amino and mono- and di-C.sub.1 -C.sub.4 -alkylamino, or represents C.sub.6 -C.sub.10 -aryl which is optionally substituted by fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, or
- B represents a radical of the formula ##STR43## wherein q represents 0, 1, 2 or 3,
- p represents 1, 2 or 3,
- (CH.sub.2).sub.p is bonded to the radical NR.sup.2 R.sup.3 and
- R.sup.17 represents hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine,
- Y represents a direct bond or a bridge member of the formula --CO--NH--, --CO--, --NH--CO--NH--, --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --CH.sub.2 --, --C(CH.sub.3).sub.2 --, ##STR44## --O--, --S--, --NH--, ##STR45## --N.dbd.N--, --NH--CO--CH.dbd.CH--CO--NH--, --NH--CO--CH.sub.2 --CH.sub.2 --CO--NH-- or ##STR46## wherein R.sup.18 represents alkyl or aryl or represents a radical of the formula ##STR47## wherein m represents 2 or 3,
- r represents 0 or 1 and
- R.sup.20, R.sup.21, R.sup.22, R.sup.23 and R.sup.24 independently of one another represent hydrogen, alkyl, alkenyl, aryl, aralkyl or cycloalkyl, or
- R.sup.21 and R.sup.22, together with the N atom to which they are bonded, form a 5- or 6-membered ring.
11 more elements
Dependencies are inferred from the claim text.