Biphenyl pyrazine compounds
AssigneeHoechst Celanese Corporation
InventorsRichard Vicari, George Kvakovszky, Olan S. Fruchey, Hans J. Metz
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Abstract
The present invention provides novel substituted biphenyl pyrazines or pyrazine derivatives ("BPD") which are functional and have useful application as a monomer for a variety of high performance polymers such as polyester, polyarylate, polycarbonate, polyetherketones, epoxides, polyimides, polyamides, and polyamides-imides; and as pigments for coating compositions such as paints. These BPD have the formula: ##STR1##
Claims14
A compound having the formula:
- ##STR26## wherein n is 1 or 3, with the proviso that A) where n is 1,
- R.sub.1 and R.sub.7 are each independently selected from the group consisting of H and --CH.sub.2 --C.sub.6 H.sub.5
- R.sub.2, R.sub.3, R.sub.6, and R.sub.8 are each independently selected from the group consisting of H, halogen, NO.sub.2 NH.sub.2, N.sub.2.sup..sym., SO.sub.3 H, SO.sub.3 M (where M is an alkali metal), C.sub.6 H.sub.5, --OR' where R' is C.sub.1-8, ##STR27## where R.sub.9 and R.sub.10 are each H, C.sub.1-6, COOCH.sub.3, and COOC.sub.2 H.sub.5, and Q.sub.1 is NH or O;
- ##STR28## where R.sub.11 is C.sub.1 -C.sub.6 ;
- ##STR29## where R.sub.12 and R.sub.13 are each independently selected from the group consisting of H, NO.sub.2, Cl, OCH.sub.3, CH.sub.3, COOH, COOCH.sub.3, NH.sub.2, ##STR30## with the proviso that at least one of R.sub.2, R.sub.3, R.sub.6, and R.sub.8 must be other than H;
- (B) where n is 3,
- R.sub.1 is ##STR31## and R.sub.2, R.sub.3, R.sub.6, R.sub.7, and R.sub.8 are the same as (A) above;
- C) where n is 1 or 3, R.sub.4 and R.sub.5 are each independently selected from the group consisting of H, NO.sub.2, NH.sub.2, and ##STR32## D) where n is 1 and R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, and R.sub.8 are H, R.sub.1, R.sub.7 are not H.
A compound of the formula:
- ##STR33##
A compound having the formula:
- ##STR34## where x and y are each independent and are either 0, 1, or 2, with the proviso that at least x or y must be 1 or 2 when the other is 0.
A compound having the formula:
- ##STR35## wherein x is selected from the group consisting of chlorine, bromine, and fluorine.
A compound having the formula:
- ##STR36##
A compound having the formula:
- ##STR37## wherein R.sub.14, R.sub.15, R.sub.16, and R.sub.17 are each independently selected from the group consisting of H, alkyl C.sub.1 -C.sub.6, COOCH.sub.3, and COOC.sub.2 H.sub.5, and Q.sub.2 is NH or O.
A compound having the formula:
- ##STR38## wherein R.sub.18 and R.sub.19 are each independently selected from the group consisting of H, alkyl C.sub.1 -C.sub.6, COOCH.sub.3, and COOC.sub.2 H.sub.5.
A compound having the formula:
- ##STR39##
Dependencies are inferred from the claim text.