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US 5,453,410 AGranted
Catalyst composition
AssigneeThe Dow Chemical Company
InventorsBrian W. S. Kolthammer, Robert S. Cardwell, John C. Tracy
Life of this patent
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Abstract
An addition polymerization catalyst comprising a cationic complex of a Group 4 metal cyclopentadienyl derivative and an alumoxane shows improved resistance to catalyst poisons.
Claims6
A catalyst composition comprising a cationic complex of the formula:
- ##STR8## wherein:
- M is a metal of Group 4 of the Periodic Table of the Elements having an oxidation state of 3 or 4, bound in an .eta..sup.5 bonding mode to Cp;
- n is zero or one, depending on the oxidation state of M;
- Cp is a cyclopentadienyl-, indenyl-, tetrahydroindenyl-, fluorenyl-, or octahydrofluorenyl- group covalently substituted with a divalent moiety, R", said divalent moiety, R", having from 1 to 50 atoms and being covalently bonded to Y, Cp further may be substituted with from 1 to 4 alkyl, halogen, aryl, haloalkyl, alkoxy, aryloxy or silyl groups containing up to 20 non-hydrogen atoms;
- Y is a divalent substituent selected from the group consisting of --NR--, --PR--, --O-- and --S--, wherein R is C.sub.1-20 hydrocarbyl, and Y together with R", Cp and M forms a metallocycle;
- X, if any, is a monovalent substituent selected from the group consisting of hydride, halo, alkyl, aryl, silyl, germyl, aryloxy, alkoxy, amide, siloxy, and phosphine groups, and combinations thereof, said groups or combination having up to 20 non-hydrogen atoms;
- and
- A.sup.- is an inert, noncoordinating anion, and an alumoxane;
- the molar ratio of alumoxane to cationic complex being from 0.1:1 to 50:1.
6 more elements
A catalyst composition comprising the reaction product of:
- a) an organometallic complex of the formula:
- ##STR11## wherein:
- M is a metal of Group 4 of the Periodic Table of the Elements having an oxidation state of +3 or +4, bound in an .eta..sup.5 bonding mode to Cp;
- n is zero or one, depending on the oxidation state of M;
- R'" is hydride or C.sub.1-20 hydrocarbyl;
- Cp is a cyclopentadienyl-, indenyl-, tetrahydroindenyl-, fluorenyl-, or octahydrofluorenyl-group, covalently substituted with a divalent moiety, R", having from 1 to 50 atoms and being covalently bonded to Y, Cp further may be substituted with from 1 to 4 alkyl, halogen, aryl, haloalkyl, alkoxy, aryloxy or silyl groups containing up to 20 non-hydrogen atoms;
- and
- Y is a divalent substituent selected from the group consisting of --NR--, --PR--, --O-- and --S--, wherein R is C.sub.1-20 hydrocarbyl, and Y together with R", Cp and M forms a metallocycle;
- and
- X, if any, is a monovalent substituent selected from the group consisting of hydride, halo, alkyl, aryl, silyl, germyl, aryloxy, alkoxy, amide, siloxy, phosphine groups, and mixtures thereof, said groups having up to 20 non-hydrogen atoms;
- b) an active compound or complex, B', capable of converting the organometallic complex a) into a cationic complex of the formula:
- ##STR12## where Cp, M, Y, X and n are as previously defined, and A.sup.- is the anion resulting from the combination of B' and R which is abstracted from complex a) or A.sup.- is the counterion from complex B';
- and
- c) an alumoxane;
- the molar ratio of b):a) being from 0.1:1 to 50:1, and the ratio of c):a) being from 1:1 to 10,000:1.
12 more elements
Dependencies are inferred from the claim text.