A product having superior wear resistance characteristics, formed from a Ti--Al system intermetallic compound, said product comprising from about 25 at. % to about 75 at. % of aluminum, from about 0.004 at. % to about 0.010 at. % of at least one halogen element selected from the group consisting of fluorine, chlorine, bromine and iodine and the remainder of said Ti--Al system intermetallic compound is titanium and unavoidable impurities;
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- said product having a dense aluminum oxide film, having a thickness between 1 .mu.m and 50 .mu.m, formed on desired surface of the product requiring wear resistance.