Organic photosensitive material for electrophotography

A photosensitive material for electrophotography comprising an electrically conducting substrate on which is provided a photosensitive layer containing

• 1 to 20 parts by weight of a charge-generating agent, a charge transporting material consisting essentially of 10 to 100 parts by weight of a diphenoquinone electron-transporting agent and 10 to 100 parts by weight of a positive hole-transporting agent, and 100 parts by weight of a binder, and
• wherein the diphenoquinone is represented by the following formula (1):
• ##STR57## wherein at least three R.sub.1 to R.sub.4 groups are different from each other and R.sub.1 is a tertiary alkyl group having 4 to 9 carbon atoms, R.sub.3 is a phenyl group or a benzyl group and R.sub.2 and R.sub.4 are primary or secondary alkyl groups or alkoxy groups having 1 to 4 carbon atoms,
• wherein the diphenoquinone is in an amount of 20 to 80% by weight based on the amount of the diphenoquinone and the positive hole-transporting agent, and
• wherein the positive hole-transporting agent is at least one member selected from the formula (2) to (11).

A photosensitive material for electrophotography comprising an electrically conductive substrate on which is provided a laminated photosensitive layer comprising

• a charge generating layer containing 50 to 500 parts by weight of a charge generating agent and 100 parts by weight of a binder, and
• an electron transporting layer containing 10 to 100 parts by weight of a diphenoquinone electron-transporting agent, 10 to 100 parts by weight of a positive hole transporting agent, and 100 parts by weight of a binder,
• wherein the diphenoquinone is represented by the following formula (1) ##STR69## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are alkyl groups, alkoxy groups, aryl groups or aralkyl groups, and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is an aryl group or an aralkyl group, and at least 2 of the remaining R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are alkyl groups or alkoxy groups,
• wherein the diphenoquinone is in an amount of 20 to 80% by weight based on the amount of the diphenoquinone and the positive hole-transporting agent, and
• wherein the positive hole-transporting agent is at least one member selected from the below formulas (2) to (11), ##STR70## wherein R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are alkyl groups, alkoxy groups, halogen atoms, aryl groups, nitro groups, cyano groups or alkylamino groups independently of each other, p and q are integers of 0 to 4, and k, l, m and o are integers of 0 to 5, ##STR71## wherein R.sub.11, R.sub.12, R.sub.13 and R.sub.14 are hydrogen atoms, alkyl groups or alkoxy groups, and n and h are integers of 1 to 3, ##STR72## wherein R.sub.15 and R.sub.17 are alkyl groups, alkoxy groups or halogen atoms, g and i are integers of 0 to 4, R.sub.16 is a hydrogen atom, an alkyl group which may have a substituent, an aralkyl group, an aryl group, or a heterocyclic group, Ar.sub.1 and Ar.sub.2 are alkyl groups, aralkyl groups, arayl groups or heterocyclic groups which may have substituents but Ar.sub.1 and Ar.sub.2 may be coupled together to form a ring except when Ar.sub.1 and Ar.sub.2 are hydrogen atoms simultaneously, and Ar.sub.3 and Ar.sub.4 are alkyl groups, aralkyl groups, aryl groups or heterocyclic rings which may have substituents but Ar.sub.3 and Ar.sub.4 may be coupled together to form a ring, ##STR73## wherein R.sub.15 and R.sub.19 are alkyl groups or an alkoxy groups, and j and r are integers of 0 to 3, ##STR74## wherein R.sub.20 is an alkyl group or an alkoxy group, Ar.sub.5, A.sub.6, Ar.sub.7 and Ar.sub.8 are hydrogen atoms, alkyl groups, alkoxy groups, aralkyl groups or aryl groups which may have a substituent, and s is an integer of 1 to 2, and t is an integer of 0 to 2, ##STR75## wherein R.sub.21 and R.sub.22 are alkyl groups or alkoxy groups, u is an integer of 0 to 2, and Ar.sub.9 and Ar.sub.10 are aryl groups which may have a substituent, ##STR76## wherein R.sub.23 is an alkyl group or an aryl group, ##STR77## wherein R.sub.24, R.sub.25, R.sub.26 and R.sub.27 are alkyl groups or alkoxy groups, and v and w are integers of 0 to 3, ##STR78## wherein R.sub.25 is an alkyl group or an aryl group, R.sub.29 and R.sub.30 are alkyl groups or alkoxy groups independently from each other, and x is an integer of 0 to 3, ##STR79## wherein R.sub.31 and R.sub.32 are alkyl groups or alkoxy groups, and y and z are integers of 0 to 3.

A photosensitive material for electrophotography comprising an organic photosensitive layer containing

• 1 to 20 parts by weight of a charge-generating agent, 10 to 100 parts by weight of a diphenoquinone electron-transporting agent, 10 to 100 parts by weight of a positive hole-transporting agent and 100 parts by weight of a binder,
• wherein the diphenoquinone is represented by the following formulas (12), (13) and (14):
• ##STR80## wherein R' is an alkyl group or an alkoxy group, R.sub.2 ' is a secondary or tertiary alkyl group, R.sub.3 ' is an aryl or an alkyl group, and R.sub.1 ', R.sub.2 ' and R.sub.3 ' are different from each other, and
• wherein the diphenoquinone is in an amount of 20 to 80% by weight based on the amount of the diphenoquinone and the positive hole-transporting agent.

A photosensitive material for electrophotography comprising an electrically conducting substrate on which is provided a photosensitive layer containing 1 to 20 parts by weight of a charge-generating agent, 10 to 100 parts by weight of a diphenoquinone electron-transporting agent, 10 to 100 parts by weight of a positive hole-transporting agent and 100 parts by weight of a binder,

• wherein the diphenoquinone is represented by the following formulas (12), (13) and (14):
• ##STR81## wherein R' is an alkyl group or an alkoxy group, R.sub.2 ' is a secondary or tertiary alkyl group, R.sub.3 ' is an aryl or an alkyl group, and R.sub.1 ', R.sub.2 ' and R.sub.3 ' are different from each other, and
• wherein the diphenoquinone is in an amount of 20 to 80% by weight based on the amount of the diphenoquinone and the positive hole-transporting agent, and
• wherein the positive hole-transporting agent is at least one member selected from the formulas (2) to (11).