Hydrogen recovery by adsorbent membranes
AssigneeAir Products and Chemicals, Inc.
InventorsMadhukar B. Rao, Shivaji Sircar, Joseph M. Abrardo, William F. Baade
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Abstract
A composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate is operated in series with a pressure swing adsorption (PSA) system and the PSA reject gas is used as a sweep gas to improve membrane performance. The integrated membrane-PSA system is particularly useful for recovering high-purity hydrogen from a mixture of hydrogen and hydrocarbons, and is well-suited for integration with a steam-methane reformer.
Claims2
An integrated separation system for the recovery of one or more primary components from a gaseous feed mixture comprising said primary components and one or more secondary components, wherein said one or more secondary components are more strongly adsorbed on an adsorbent material than said primary components, said system comprising:
- (a) one or more separator modules each containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, each membrane having a feed side and a permeate side, wherein said microporous adsorbent material is capable of selective adsorption and permeation of said one or more secondary components;
- (b) a pressure swing adsorption system comprising a plurality of adsorbent vessels containing granular adsorbent material capable of selectively adsorbing said one or more secondary components;
- (c) means for introducing said gaseous feed mixture into each of said one or more separator modules on the feed side of said membrane;
- (d) means for removing a nonpermeate intermediate product stream from the feed side of said membrane from each of said one or more separator modules, and means for introducing said stream into said pressure swing adsorption system;
- (e) means for removing a high purity product stream comprising said primary components and means for removing a reject stream comprising said one or more secondary components from said pressure swing adsorption system;
- (f) means for introducing at least a portion of said reject stream into each of said one or more separator modules and passing the portions of said reject stream over the permeate side of each membrane as a sweep gas;
- and
- (g) means for withdrawing from said one or more separator modules a mixed sweep gas/permeate stream.
Dependencies are inferred from the claim text.