Coating a composite article by applying a porous particulate layer and densifying the layer by subsequently applying a ceramic layer

A process for applying a coating to a composite article having a ceramic matrix said matrix having surface porosity, the process comprising:

• a. forming a green coating on the composite article by applying to the surface of the matrix of the composite a mixture of particles having diameters in the range of 0.05 to 50 micrometers and a curable liquid polymeric silicon-containing binder, said binder being present in the mixture in an amount of from about 1 to about 25% by weight of said particles;
• b. curing the green coating by heating the coating;
• and
• c. infiltrating and covering the porous layer with a ceramic layer by chemical vapor infiltration;
• and
• wherein said particles are selected from the group consisting of boron carbide, silicon carbide, silicon boride, calcium boride, tantalum boride, niobium boride, hafnium boride, aluminum boride, zirconium boride, rare-earth borides, yttrium boride, germanium boride, germanium silicide, titanium silicide, titanium boride, metallic silicides and mixed phase boride/silicide combinations;
• and
• wherein said ceramic matrix of the composite article is selected from the group consisting of silicon carbide and silicon nitride, said curable binder is selected from the group consisting of polycarbosilanes and polysilazanes, and said ceramic layer is selected from the group consisting of silicon carbide and silicon nitride.