Purification of oxygen by cryogenic adsorption
AssigneeThe BOC Group, Inc.
InventorsRavi Jain, Alberto LaCava
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Abstract
Apparatus and a process for producing high purity oxygen containing not more than 1 ppm by volume of hydrocarbons. An oxygen stream containing up to about 100 ppm by volume of hydrocarbons is subjected to cryogenic temperature swing adsorption in an adsorption bed containing calcium-exchanged type X zeolite, type 5A zeolite or 13X zeolite, for the removal of the hydrocarbons and any nitrogen present in the oxygen stream.
Claims22
A temperature swing adsorption process for removing impurities selected from the group consisting of hydrocarbons, nitrogen and mixtures thereof from a gaseous oxygen feed stream comprising the step of passing said feed stream through a bed of hydrocarbon- and nitrogen-selective adsorbent at a temperature below about 150.degree. K., thereby producing a substantially hydrocarbon- and nitrogen-free oxygen product stream.
A temperature swing adsorption process for removing hydrocarbons from a gaseous air stream containing at least one hydrocarbon as an impurity comprising the step of passing said gaseous air stream through a bed of hydrocarbon-selective adsorbent at a temperature below about 150.degree. K., thereby producing a substantially hydrocarbon-free air stream.
A temperature swing adsorption process for producing an oxygen product stream containing not more than 1 ppm hydrocarbon from air containing up to about 100 ppm of total hydrocarbons as impurities comprising the steps of:
- (a) cryogenically distilling said air, thereby producing an oxygen-enriched gaseous stream containing said hydrocarbons;
- and
- (b) adsorbing hydrocarbons from said oxygen-enriched gaseous stream by passing said oxygen-enriched gaseous stream through a bed of hydrocarbon-selective adsorbent at a temperature below about 150.degree. K.
A temperature swing adsorption process for producing an oxygen product stream containing not more than 1 ppm hydrocarbon from an air stream containing up to about 100 ppm hydrocarbons as an impurity comprising the steps of:
- (a) passing said air stream through a bed of hydrocarbon-selective adsorbent at a temperature below about 150.degree. K., thereby producing substantially hydrocarbon-free air;
- and
- (b) cryogenically distilling the substantially hydrocarbon-free air, thereby producing a substantially hydrocarbon-free oxygen-enriched stream.
Apparatus for producing high purity oxygen from air which contains hydrocarbon as an impurity comprising:
- (a) a distillation column having an air inlet means, a gaseous oxygen-enriched stream outlet means and a gaseous nitrogen-enriched stream outlet means;
- and
- (b) cryogenic temperature swing adsorption means comprising an adsorbent bed containing at least one hydrocarbon-selective adsorbent, inlet means in fluid communication with said gaseous oxygen-enriched stream outlet means, nonadsorbed product gas outlet means and desorbed product gas outlet means.
Apparatus for producing high purity oxygen from air which contains hydrocarbon as an impurity comprising:
- (a) cryogenic temperature swing adsorption means comprising an adsorbent bed containing at least one hydrocarbon-selective adsorbent and having nonadsorbed product gas outlet means and desorbed product gas outlet means;
- and
- (b) a distillation column having an air inlet means in fluid communication with said nonadsorbed product gas outlet means, a gaseous oxygen-enriched stream outlet means and a gaseous nitrogen-enriched stream outlet means.
Dependencies are inferred from the claim text.