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US 5,414,102 AGranted
Fluorinated carboxylic acid esters of phosphono- and phosphinocarboxylic acids containing acrylate and/or methacrylate groups
AssigneeBayer Aktiengesellschaft
InventorsKlaus Pohmer, Rainer Weber, Hans-Dieter Block, Hans-Heinrich Moretto
Life of this patent
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Abstract
The present invention relates to fluorinated carboxylic acid esters of phosphonocarboxylic acids containing acrylate and/or methacrylate groups, their use as waterproofing or oil-repellency agents, and a method for their preparation.
Claims6
Fluorinated carboxylic acid esters of phosphono- or phosphinocarboxylic acids containing acrylate and/or methacrylate groups, of formula (I) ##STR9## wherein:
- R.sup.1 is a hydroxyl group, a methyl group, an ethyl group or a phenyl radical,
- R.sub.F is a linear or branched fluoroalkyl radical with 1 to 18 carbon atoms, or a fluorinated branched or linear monomeric ether or polyether with 1 to 18 carbon atoms,
- R.sub.H is a linear or branched alkyl radical with 1 to 10 carbon atoms,
- R is an acrylate group of structure ##STR10## or a methacrylate group of structure ##STR11## Y represents a ##STR12## Z represents a linear or branched alkanetriyl radical (trivalent hydrocarbon radical) with 1 to 20 carbon atoms, or
- a radical of the formula ##STR13## or a linear or branched alkanetriyl radical with 1 to 20 carbon atoms with one or more substituent groups of structure COR.sup.2, or
- a linear or branched alkanetriyl radical with 1 to 20 carbon atoms with one or more substituent groups of structure --PO.sub.2 HR.sup.1, where R.sup.1 has the same meaning as above,
- m is 0 or 1,
- n is an integer from 0 to 6,
- is an integer from 0 to 6, and
- R.sup.2 represents a hydroxyl radical or a radical of structure ##STR14## or a radical of structure O--(CH.sub.2).sub.o --R, or a linear or branched alkoxy radical with 1 to 30 carbon atoms, where n, m, o, R.sub.H, R.sub.F and Y have the same meaning as above,
- and their salts.
8 more elements
Dependencies are inferred from the claim text.