Colorant and ink compositions

Colorant compositions selected from the group consisting of:

• (a) dimeric compounds containing one moiety of Formula I and one moiety of Formula II, wherein Formula I is as follows:
• ##STR66## wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• and Formula II is as follows:
• ##STR67## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (b) trimeric compounds containing three moieties of Formula II;
• (c) trimeric compounds containing two moieties of Formula I and one moiety of Formula II;
• (d) trimeric compounds containing one moiety of Formula I and two moieties of Formula II;
• (e) polymeric compounds containing at least four moieties selected from the group consisting of Formula I, Formula II, and mixtures thereof;
• (f) dimeric compounds containing two moieties of Formula III ##STR68## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, and substituted alkyl, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• and (g) dimeric compounds containing two moieties of Formula IV ##STR69## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl.

A process which entails (a) incorporating into an ink jet printing apparatus an ink composition which comprises water, a humectant, and a colorant selected from the group consisting of:

• (a) those of Formula I ##STR70## wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (b) those of Formula II ##STR71## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (c) dimeric compounds containing two moieties of Formula I;
• (d) dimeric compounds containing two moieties of Formula II;
• (e) dimeric compounds containing one moiety of Formula I and one moiety of Formula II;
• (f) trimeric compounds containing three moieties of Formula I;
• (g) trimeric compounds containing three moieties of Formula II;
• (h) trimeric compounds containing two moieties of Formula I and one moiety of Formula II;
• (i) trimeric compounds containing one moiety of Formula I and two moieties of Formula II;
• (j) polymeric compounds containing at least four moieties selected from the group consisting of Formula I, Formula II, and mixtures thereof;
• and (k) mixtures thereof;
• and (b) causing droplets of the ink composition to be ejected in an imagewise pattern onto a substrate.

An aqueous ink composition for ink jet printing which comprises water, a humectant, and a colorant selected from the group consisting of:

• (a) the following formulae, wherein R.sub.1 and R'1 are each electron withdrawing groups, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 and R'3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and X is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR75## (b) those of the following formulae, wherein R.sub.1 and R'.sub.1 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Y is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR76## (c) those of the following formulae, wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R'.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R'.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar' is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Z is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR77## and (d) mixtures thereof.

A colorant selected from the group consisting of:

• (a) the following formulae, wherein R.sub.1 and R'1 are each electron withdrawing groups, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 and R'3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and X is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR78## those of the following formulae, wherein R.sub.1 and R'.sub.1 are each selected from the group consisting of cyano groups, nitro-aromatic groups, acid groups, amide groups, aldehyde, groups, ketone groups, and --N+(CH.sub.2 CH.sub.2 OH).sub.3, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 and R'.sub.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and X is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR79## (c) those of the following formulae, wherein R.sub.1 and R'.sub.1 are each electron withdrawing groups, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 and R'.sub.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and X is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR80## (d) those of the following formulae, wherein R.sub.1 and R'.sub.1 are each electron withdrawing groups, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 and R'.sub.3 are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and X is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR81## (e) those of the following formulae, wherein R.sub.1 and R'.sub.1 are each independently selected from the group consisting of hydrogen, alkyl, and substituted alkyl, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Y is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR82## (f) those of the following formulae, wherein R.sub.1 and R'.sub.1 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 and R'.sub.2 are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar and Ar' are each independently selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Y is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR83## (g) those of the following formulae, wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R'.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R'.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, Ar' is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Z is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl:
• ##STR84## and (h) mixtures thereof.

A process which comprises (a) providing a donor element comprising a substrate and a dye selected from the group consisting of:

• (a) those of Formula I ##STR88## wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (b) those of Formula II ##STR89## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (c) dimeric compounds containing two moieties of Formula I;
• (d) dimeric compounds containing two moieties of Formula II;
• (e) dimeric compounds containing one moiety of Formula I and one moiety of Formula II;
• (f) trimeric compounds containing three moieties of Formula I;
• (g) trimeric compounds containing three moieties of Formula II;
• (h) trimeric compounds containing two moieties of Formula I and one moiety of Formula II;
• (i) trimeric compounds containing one moiety of Formula I and two moieties of Formula II;
• (j) polymeric compounds containing at least four moieties selected from the group consisting of Formula I, Formula II, and mixtures thereof;
• and (k) mixtures thereof;
• and (b) applying heat imagewise to the donor element, thereby causing dye to transfer in imagewise fashion from the donor element to a substrate.

A process which comprises (a) providing a donor element comprising a substrate and a dye selected from the group consisting of:

• (a) those of Formula I ##STR90## wherein R.sub.1 is an electron withdrawing group, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.3 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (b) those of Formula II ##STR91## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, R.sub.2 is selected from the group consisting of hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, and substituted arylalkyl, and Ar is selected from the group consisting of aryl, substituted aryl, arylalkyl, and substituted arylalkyl;
• (c) dimeric compounds containing two moieties of Formula I;
• (d) dimeric compounds containing two moieties of Formula II;
• (e) dimeric compounds containing one moiety of Formula I and one moiety of Formula II;
• (f) trimeric compounds containing three moieties of Formula I;
• (g) trimeric compounds containing three moieties of Formula II;
• (h) trimeric compounds containing two moieties of Formula I and one moiety of Formula II;
• (i) trimeric compounds containing one moiety of Formula I and two moieties of Formula II;
• (i) polymeric compounds containing at least four moieties selected from the group consisting of Formula I, Formula II, and mixtures thereof;
• and (k) mixtures thereof;
• and (b) applying heat imagewise to the donor element, thereby causing dye to transfer in imagewise fashion from the donor element to a substrate, wherein heat is applied to the donor element by a laser, wherein the donor element contains a material which absorbs strongly at the wavelength of the laser thereby converting light energy to thermal energy when irradiated with the laser, and wherein the dye is heated to a temperature at or above its vaporization temperature, thereby causing the dye to transfer from the donor element to the substrate in imagewise fashion.