US 5,403,499 AGranted

Concentrated fabric conditioning compositions

AssigneeLever Brothers Company, Division of Conopco, Inc.

InventorsJesse J. Kiefer, Lucia V. Salas, Dian M. Najarian

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Abstract

An aqueous concentrated fabric conditioning composition is prepared by adding the co-melted mixture of cationic and nonionic agents to an acid solution. The resulting compositions are stable, have a viscosity of less than 300 cps, a pH of less than 4.0 and an average particle size of from about 2 to about 8 microns.

Claims7

Dependent claims

A process for the preparation of a concentrated aqueous composition containing

A. from about 2 to about 11% by weight of a first conditioner agent selected from the group consisting of ##STR15## wherein R.sub.1 and R.sub.2 can be the same or different from each other and are selected from the group consisting of C.sub.14 to C.sub.22 alkyl, alkenyl or ester-linked alkyl or alkenyl groups, and R.sub.3 is selected from the group consisting of C.sub.1 to C.sub.4 alkyls, or C.sub.n H.sub.2n O.sub.x H wherein n is 2 or 3 and x is from 1 to about 3, and wherein X.sup.31 is an anion selected from a group consisting essentially of a halide or alkyl sulfate having from 1 to 3 carbon atoms in the alkyl chain, or ##STR16## wherein R.sub.4 and R.sub.5 are each an alkyl or alkenyl chain containing from 11 to 23 carbon atoms;
and R.sub.6 and R.sub.7 are each an alkyl or hydroxy alkyl group containing from 1 to 4 carbon atoms;
B. from about 2 to about 28% by weight of a second cationic softener selected from the group consisting of ##STR17## wherein R.sub.8 and R.sub.9 are the same as each other or different and are selected from the group consisting of C.sub.14 to C.sub.22 alkyl or alkenyl groups, and R.sub.10 is selected from the group consisting of (C.sub.n H.sub.2n O).sub.x H wherein n is 2 or 3 and x is from 1 to about 3, and wherein X.sup.- is an anion, selected from a group consisting of halides, sulfates, acetates or alkyl sulfates having from 1 to 3 carbon atoms in the alkyl chain;
and
C. from about 0.02% to about 16% of a nonionic conditioning agent selected from the group consisting of a formula ##STR18## wherein R.sub.8 , R.sub.9 and R.sub.10 are as defined above, or an imidazoline selected from the group consisting of formula ##STR19## wherein R.sub.11, R.sub.12, R.sub.13, R.sub.14 and R.sub.15 are as defined above, wherein all three components A, B and C are free of an inorganic salt selected from the group consisting of sodium methosulfate, potassium methosulfate, sodium chloride, potassium chloride and mixtures thereof and the total amount of components A+B+C is from about 23% to about 35%, the final pH of the composition is less than 4.0, and an average particle size of the composition is about 2 to about 8 microns, the said process comprising the steps of:
(a) co-melting components A, B and C together at a temperature which is above the melting temperature of the highest melting component to form a homogeneous premix;
(b) adding an effective amount of a Bronstedt acid having a pK.sub.a equal to or less than 4.0 or an aqueous solution thereof to water at a temperature at or slightly below the temperature of the premix to obtain an acidic solution used to obtain a final composition pH below 4.0;
(c) adding the premix to the acidic solution at a mixing speed between about 1 m/sec and 3 m/sec to form a homogeneous mixture;
(d) adding an effective amount of an inorganic salt or an aqueous solution thereof to the homogeneous mix to obtain a viscosity of the final composition between about 20 and about 300 centipoises using a Brookfield Spindle#1 at 12 rpm;
and
(e) optionally adding one or more additives selected from the group consisting of perfume, silicone emulsions, dyes, pigments, opacifiers, germicides, optical brighteners, any anti-corrosive agents and preservatives, the amount of each additive being up to 2.0% by weight of the composition.

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Dependencies are inferred from the claim text.

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Abstract

A process for the preparation of a concentrated aqueous composition containing

A. from about 2 to about 11% by weight of a first conditioner agent selected from the group consisting of ##STR15## wherein R.sub.1 and R.sub.2 can be the same or different from each other and are selected from the group consisting of C.sub.14 to C.sub.22 alkyl, alkenyl or ester-linked alkyl or alkenyl groups, and R.sub.3 is selected from the group consisting of C.sub.1 to C.sub.4 alkyls, or C.sub.n H.sub.2n O.sub.x H wherein n is 2 or 3 and x is from 1 to about 3, and wherein X.sup.31 is an anion selected from a group consisting essentially of a halide or alkyl sulfate having from 1 to 3 carbon atoms in the alkyl chain, or ##STR16## wherein R.sub.4 and R.sub.5 are each an alkyl or alkenyl chain containing from 11 to 23 carbon atoms;
and R.sub.6 and R.sub.7 are each an alkyl or hydroxy alkyl group containing from 1 to 4 carbon atoms;
B. from about 2 to about 28% by weight of a second cationic softener selected from the group consisting of ##STR17## wherein R.sub.8 and R.sub.9 are the same as each other or different and are selected from the group consisting of C.sub.14 to C.sub.22 alkyl or alkenyl groups, and R.sub.10 is selected from the group consisting of (C.sub.n H.sub.2n O).sub.x H wherein n is 2 or 3 and x is from 1 to about 3, and wherein X.sup.- is an anion, selected from a group consisting of halides, sulfates, acetates or alkyl sulfates having from 1 to 3 carbon atoms in the alkyl chain;
and
C. from about 0.02% to about 16% of a nonionic conditioning agent selected from the group consisting of a formula ##STR18## wherein R.sub.8 , R.sub.9 and R.sub.10 are as defined above, or an imidazoline selected from the group consisting of formula ##STR19## wherein R.sub.11, R.sub.12, R.sub.13, R.sub.14 and R.sub.15 are as defined above, wherein all three components A, B and C are free of an inorganic salt selected from the group consisting of sodium methosulfate, potassium methosulfate, sodium chloride, potassium chloride and mixtures thereof and the total amount of components A+B+C is from about 23% to about 35%, the final pH of the composition is less than 4.0, and an average particle size of the composition is about 2 to about 8 microns, the said process comprising the steps of:
(a) co-melting components A, B and C together at a temperature which is above the melting temperature of the highest melting component to form a homogeneous premix;
(b) adding an effective amount of a Bronstedt acid having a pK.sub.a equal to or less than 4.0 or an aqueous solution thereof to water at a temperature at or slightly below the temperature of the premix to obtain an acidic solution used to obtain a final composition pH below 4.0;
(c) adding the premix to the acidic solution at a mixing speed between about 1 m/sec and 3 m/sec to form a homogeneous mixture;
(d) adding an effective amount of an inorganic salt or an aqueous solution thereof to the homogeneous mix to obtain a viscosity of the final composition between about 20 and about 300 centipoises using a Brookfield Spindle#1 at 12 rpm;
and
(e) optionally adding one or more additives selected from the group consisting of perfume, silicone emulsions, dyes, pigments, opacifiers, germicides, optical brighteners, any anti-corrosive agents and preservatives, the amount of each additive being up to 2.0% by weight of the composition.

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