# US 5,401,813 A · Transparent polycarbonate PBT blends

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- Number: US 5,401,813 A
- Document ID: US5401813A
- Status: Granted
- Kind: A
- Application number: 08/151,435
- Filed: 1993-11-12
- Granted: 1995-03-28
- Earliest claimed: 1993-11-12
- Assignees: Miles Inc.
- Inventors: James P. Mason
- Web page: https://patentgrep.com/patent/US5401813A

## CPC

- C08L 67/02: Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence)
- C08L 69/00: Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

Thermoplastic molding compositions containing (i) polybutylene terephthalate (ii) a first aromatic polycarbonate resin, and (iii) a second aromatic polycarbonate resin are disclosed. A high level of Total Light Transmission (herein TLT) is a key characteristic of the compositions of the invention. Preferably, the TLT values of the compositions are higher than those of compositions which contain only said (i) and either (ii) or (iii). Most preferably, the TLT values of the compositions are higher than 80%.

## Claims

### Claim 1

A method for increasing the TLT value of a thermoplastic molding composition which contains 1 to 30 % relative to its weight of polybutylene terephthalate the balance being either one of (i) a first aromatic polycarbonate resin or (ii) a second aromatic polycarbonate resin, comprising substituting at least some of said balance by the complementary component selected from said (ii) and said (i), to form a blend containing polybutylene terephthalate, (i) and (ii), wherein each of said (i) and said (ii) is present in the composition having increased TLT value in an amount of 20 to 60% by weight, said second aromatic polycarbonate resin being different from said first aromatic polycarbonate resin in that it contains about 10 to 100% structural units derived from a dihydroxy compound having a bridging unit corresponding to ##STR7## wherein R.sup.3 and R.sup.4 independently one of the other represents a hydrogen atom or a C.sub.1-6 alkyl and X denotes carbon, with the proviso that R.sup.3 and R.sup.4 both represent an alkyl radical on at least one of the X carbon atoms, and where m is an integer of 4 to 10, said TLT being determined in accordance with ASTM D-1003 using specimens 0.100" in thickness.

### Claim 2 (depends on 1)

The composition prepared in accordance with the method of claim 1.

### Claim 3 (depends on 2)

The composition of claim 2 wherein said first aromatic polycarbonate resin is derived from a dihydroxy compound conforming to formula (1) or (2) ##STR8## wherein A denotes an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, a carbonyl group, an oxygen atom, --S--, --SO-- or --SO.sub.2 -- radical or a radical conforming to ##STR9## and wherein g denotes 0 or 1, e denotes 0 or 1, d denotes 0 to 4 and f denotes 0 to 3, and where the several Z substituents independently one of the other denotes F, Cl, Br or an alkyl group having 1 to 4 carbon atoms.