Poly(alkylene cyclohexanedicarboxylate)-(alkylene terephthalate) copolyesters
AssigneeGeneral Electric Company
InventorWillem F. H. Borman
Life of this patent
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Abstract
Copolyester compositions are provided which comprise the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or a chemical equivalent thereof, a mixture of at least two cycloaliphatic diacids or chemical equivalents thereof, the mixture comprising predominantly a trans-enantiomer, and at least one aromatic diacid or a chemical equivalent thereof. These copolyesters have superior ductility to the homopolymers of the diol component and either of the diacid components.
Claims9
A thermoplastic copolyester composition having improved ductility, mold flow, and rate of crystallization, and a melting point of about 161.degree. C. or higher, comprising the reaction product of (A) at least one alkane diol selected from the group consisting of straight chain, branched, and cycloaliphatic C.sub.2 -C.sub.10 alkane diols;
- (B) a mixture of at least two cycloaliphatic diacids;
- said mixture comprising from about 0.5 to about 49 parts by weight of a cis-enantiomer and from about 51 to about 99.5 parts by weight of a trans-enantiomer, the parts by weight of the cis-enantiomer and the trans-enantiomer being based upon 100 parts by weight of the cis- and trans-enantiomers combined;
- and (C) at least one aromatic diacid;
- wherein the molar ratio of cycloaliphatic diacid to aromatic diacid thereof ranges from 1:9 to 1:1, wherein said copolyester has recurring units of the formula ##STR3## wherein R represents residue of the alkane diol, R' represents the decarboxylated residue derived from the cycloaliphatic diacids, and R" represents an aromatic radical which is the decarboxylated residue of the aromatic diacid, and wherein the x units comprise from 10 to 90 parts by weight and the y units comprise from 90 to 10 parts by weight of 100 parts by weight of the copolyester.
A composition as defined in claim 4 wherein said mixture of cycloaliphatic diacids (B) comprises a mixture of cis- and trans-1,4-cyclohexane dicarboxylic acid.
Dependencies are inferred from the claim text.