Two-stage process for the production of thermoplastic polycarbonate

A two-stage process for the production of lightly branched polycarbonate by transesterification of diphenols, carbonic acid diaryl esters and catalysts comprising in the melt at temperatures of 80.degree. C. to 320.degree. C. under pressures of 1,000 mbar to 0.01 mbar, characterized in that the process is carried out in two stages and in that at least one member selected from a first group, said first group consisting of quaternary ammonium and phosphonium compounds, is used as catalyst in the first stage of the process (oligocarbonate synthesis) in quantities of 10.sup.-4 to 10.sup.-8 mol per mol diphenol, the melting of the reactants in the first stage taking place over a period of up to 5 hours under atmospheric pressure at temperatures in the range from 80.degree. C. to 180.degree. C.;

• an oligocarbonate is produced by distilling off monophenols after addition of the catalyst, application of vacuum (from 1 bar to 0.5 mbar) and an increase in temperature (up to 290.degree. C.) and the oligocarbonate thus produced is polycondensed to the polycarbonate in shod times (less than 3 hours) in the second stage with addition of at least one member selected from a second group, said second group consisting of alkali metal and alkaline earth metal catalysts, in quantities of 10.sup.-4 to 10.sup.-8 mol per mol diphenol at temperatures in the range from 240.degree. C. to 320.degree. C. and under pressures of <500 mbar to 0.01 mbar wherein branching agent corresponding to formula (1) ##STR5## in which X=C.sub.1-8 alkylidene or C.sub.5-10 cycloalkylidene, S or a single bond;
• R=CH.sub.3, Cl or Br, and
• n=0, 1 or 2,
• as determined by total saponification using HPLC does not exceed 75 ppm.