A process for forming a microcapsule which comprises allowing at least a first capsule shell-forming monomer and a second capsule shell-forming monomer to undergo reaction inside and/or on the interface of oil drops to form capsule shells, said oil drops containing a pigment, an organic solvent, and at least one isocyanate-containing organosilicon compound selected from silylisocyanate derivatives represented by formulae (I), (II) and (III) and condensates thereof:
- R.sub.p R'.sub.q R".sub.r Si(NCO).sub.4-p-q-r (I)
- (RO).sub.p (R'O).sub.q (R"O).sub.r Si(NCO).sub.4-p-q-r (II)
- R.sub.x (R'O).sub.y Si(NCO).sub.z (III)
- wherein R, R' and R" each represents an alkyl group, an aryl group or an alkenyl group;
- p, q and r, which each represents 0 or an integer of from 1 to 3, satisfy the relationship (p+q+r<3);
- and x, y and z, which each represents an integer 1 or 2, satisfy the equation (x+y+z=4).