Process for trichromatic dyeing or printing
AssigneeCiba-Geigy Corporation
InventorJean-Marie Adam
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AssigneeCiba-Geigy Corporation
InventorJean-Marie Adam
Estimating the term…
Process for the trichromatic dyeing or printing of natural or synthetic polyamide fibre materials, which comprises using at least one blue-dyeing anthraquinone dye of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or C.sub.1 -C.sub.6 alkyl, the sum of the carbon atoms of the radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 being 4, 5 or 6 and the sulfo group in the anthraquinone dye of the formula (1) being attached in the position designated as 6 or 7, together with at least one red-dyeing dye of the formula (2) and at least one of the yellow- or orange-dyeing dyes of the formulae (3), (4) and (5), the dyes of the formulae (2), (3), (4) and (5) being as defined in claim 1. The process according to the invention is suitable for dyeing natural or synthetic polyamide materials from an aqueous liquor or for printing with printing pastes.
A process for the trichromatic dyeing or printing of natural or synthetic polyamide fibre materials, which comprises using at least one blue-dyeing anthraquinone dye of the formula ##STR16## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or C.sub.1 -C.sub.6 alkyl, the sum of the carbon atoms of the radicals R.sub.1, R.sub.2, R.sub.3 and R4 being 4, 5 or 6 and the sulfo group in the anthraquinone dye of the formula (1) being attached in the position designated as 6 or 7, together with at least one red-dyeing dye of the formula ##STR17## in which R.sub.5 is phenyl or cyclohexyl and R.sub.6 is C.sub.1 -C.sub.4 alkyl, or the radicals R.sub.5 and R.sub.6 together with the nitrogen atom linking them form an azepinyl ring, and at least one of the yellow- or orange-dyeing dyes of the formulae (3), (4) and (5) ##STR18## in which R.sub.7 and R.sub.8 independently of one another, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, R.sub.10 is sulfo, C.sub.2 -C.sub.4 alkanoylamino, halogen or sulfo, R.sub.9 is hydrogen or C.sub.1 -C.sub.4 alkyl, and n is 1, 2, 3 or 4, ##STR19## in which B.sub.1, B.sub.2 and E.sub.1 are hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and X is straight-chain or branched C.sub.1 -C.sub.4 alkyl or straight-chain or branched C.sub.2 -C.sub.4 hydroxyalkyl, ##STR20## in which W.sub.1 is phenylsulfonyl which is unsubstituted or substituted in the phenyl ring by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, W.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, W.sub.3 is C.sub.1 -C.sub.4 alkyl or unsubstituted or C.sub.1 -C.sub.4 alkyl-, C.sub.1 -C.sub.4 alkoxy- or halogen-substituted phenyl, and W.sub.4 is hydrogen or C.sub.1 -C.sub.8 alkyl.
A dye mixture, which comprises at least one blue-dyeing anthraquinone dye of the formula ##STR24## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen or C.sub.1 -C.sub.6 alkyl, the sum of the carbon atoms of the radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 being 4, 5 or 6 and the sulfo group in the anthraquinone dye of the formula (1) being attached in the position designated as 6 or 7, together with at least one red-dyeing dye of the formula ##STR25## in which R.sub.5 is phenyl or cyclohexyl and R.sub.6 is C.sub.1 -C.sub.4 alkyl, or the radicals R.sub.5 and R.sub.6 together with the nitrogen atom linking them form an azepinyl ring, and at least one of the yellow- or orange-dyeing dyes of the formulae (3), (4) and (5) ##STR26## in which R.sub.7 and R.sub.8 independently of one another, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or sulfo, R.sub.9 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.10 is sulfo, and n is 1, 2, 3 or 4, ##STR27## in which B.sub.1, B.sub.2 and E.sub.1 are hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and X is straight-chain or branched C.sub.1 -C.sub.4 alkyl or straight-chain or branched C.sub.2 -C.sub.4 hydroxyalkyl, ##STR28## in which W.sub.1 is phenylsulfonyl which is unsubstituted or substituted in the phenyl ring by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, W.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, W.sub.3 is C.sub.1 -C.sub.4 alkyl or unsubstituted or C.sub.1 -C.sub.4 alkyl-, C.sub.1 -C.sub.4 alkoxy- or halogen-substituted phenyl, and W.sub.4 is hydrogen or C.sub.1 -C.sub.8 alkyl.
Dependencies are inferred from the claim text.