Thermoplastic polyester compositions and films formed using same
AssigneeToray Industries, Inc.
InventorsMasahiro Kimura, Tomoji Saeki, Masaru Suzuki, Minoru Yoshida, Toshihiro Sasaki
Life of this patent
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Abstract
The thermoplastic polyester compositions of the present invention are characterized by containing special colloidal silica particles having a straight-chain or branched shape, so when formed into film, particularly film for magnetic tape, there are attained superior abrasion resistance, scratch resistance and sliding property.
Claims15
A thermoplastic polyester composition comprising a thermoplastic polyester and colloidal silica particles,
- said colloidal silica particles having a ratio of a particle diameter (D.sub.1 m.mu.) measured by a dynamic light by a nitrogen gas absorbing method, D.sub.1 /D.sub.2, of 2 or more, D.sub.1 being in the range of 60 to 600 m.mu., further having a thickness in the range of 41 to 100 m.mu. is observation using an electron microscope, and having a straight-chain or branched shape, wherein said silica particles are substantially free of agglomerations.
A thermoplastic polyster composition prepared by adding a slurry of the following components (a), (b) and (c) in any polyester production stage:
- (a) colloidal silica particles having a ratio of a particle diameter (D.sub.1 m.mu.) measured by a dynamic light scattering method to a particle diameter (D.sub.2 m.mu.) measured by a nitrogen gas absorbing method, D.sub.1 /D.sub.2, or more, D.sub.1 being in the range of 60 to 600 m.mu., further having a thickness in the range of 41 to 100 m.mu. is observation using an electron microscope, and having a straight-chain or branched shape, said silica particles being substantially free of agglomerations, (b) 50 to 3,000 ppm (weight ratio) as SO.sub.3, relative to the SiO.sub.2 which constitutes said colloidal silica particles, of a sulfur atom-containing compound, (c) 1,000 to 20,000 ppm (weight ratio) as Na.sub.2 O, relative to the SiO.sub.2 which constitutes said collidal silica particles, of Na atom.
Dependencies are inferred from the claim text.