Resin composition and coating composition containing the same
AssigneeNippon Paint Co., Ltd.
InventorsYoshitaka Okude, Tsuneyoshi Hisai, Akira Fushimi, Kazuhiko Takeoka, Seigo Miyazoe
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Abstract
The present invention provides a thermosetting resin composition which provides cured film having not only excellent acid resistance but also good weather resistance, good mar resistance and high water repellency. The thermosetting resin composition comprises (a) a fluorinated polymer having a hydroxyl group and/or an acid group, (b) a polymer having a carboxyl group and a carboxylic ester, and (c) a polymer having a hydroxyl group and an epoxy group.
Claims3
In a process of forming a coating on a substrate, comprising applying a colored base of a water-borne or solvent-borne coating on a primered or intercoated substrate, and then applying a clear top coat without curing the base layer, and then baking both the base and clear coating layers to cure;
- the improvement comprising applying as the clear top coat a thermosetting resin composition comprising the following components:
- (a) from about 0.5 to 40% by weight of a fluorinated polymer having a hydroxyl group and/or an acid group, represented by:
- ##STR4## wherein said R.sub.1 represents a linear or branched alkyl group or an alkyloyl group, having 2 to 10 carbon atoms, R.sub.2 represents an alkylene group having 2 to 10 carbon atoms, R.sub.3 represents a hydrogen atom or --CO--R.sub.6 --COOH in which R.sub.6 represents a residue of a dibasic acid anhydride, X is a hydrogen atom, a chlorine atom or a fluorine atom, a, b and c are integers satisfying a.ltoreq.b+c,
- (b) from about 10 to 60% by weight of a polymer having a carboxyl group and a carboxylic ester, prepared by copolymerizing from about 15 to 40% by weight of an ethylenically unsaturated monomer having an acid anhydride group, and from about 60 to 85% by weight of another ethylenically unsaturated copolymerizable monomer to obtain a polymer having acid anhydride groups which are then reacted with a hydroxyl compound having 1 to 12 carbon atoms in a molar ratio of acid anhydride group to hydroxyl group of from about 1/1 to 1/1.5% by weight of monomers being based on total monomer weight, and
- (c) from about 30 to 60% by weight of a polymer having a hydroxyl group and an epoxy group, prepared by copolymerizing:
- (i) from about 5 to 40% by weight of a hydroxyalkyl (meth)acrylate represented by:
- ##STR5## wherein R represents a hydrogen atom or a methyl group and n is an integer of 2 to 8,
- (ii) from about 10 to 60% by weight of an epoxy group-containing ethylenically unsaturated monomer, and
- (iii) from about 0 to 85% by weight of another copolymerizable ethylenically unsaturated monomer;
- the % by weight being based on total monomer weight.
Dependencies are inferred from the claim text.