Lewis acid catalyzed ammonolysis of nylon

A process for preparing a mixture of monomers comprising reacting a polyamide or mixture of polyamides with at least 1 equivalent of ammonia per amide group of the polymer at a temperature between 250.degree. and 400.degree. C. and at a pressure of at least 100 psig, characterized in that the reaction is carried out in the presence of a Lewis acid catalyst precursor and in the absence of hydrogen, wherein the Lewis Acid is a complex containing an element selected from scandium, titanium, yttrium, and zirconium, and at least one anion whose conjugate acid has a pKa<20.

A process for preparing a mixture of monomers comprising reacting a polyamide or mixture of polyamides with at least 1 equivalent of ammonia per amide group of the polymer at a temperature between 250.degree. and 400.degree. C. and at a pressure of at least 100 psig, characterized in that the reaction is carried out in the presence of a Lewis acid catalyst precursor and in the absence of hydrogen, wherein the Lewis Acid is a complex containing a metal selected from the metals listed in Groups 5-14 of the Periodic Table, and at least one anion whose conjugate acid has a pKa<4.

A process for preparing a mixture of monomers comprising reacting a polyamide or mixture of polyamides with at least 1 equivalent of ammonia per amide group of the polymer at a temperature between 250.degree. and 400.degree. C. and at a pressure of at least 100 psig, characterized in that the reaction is carried out in the presence of a Lewis acid catalyst precursor and in the absence of hydrogen, wherein the Lewis Acid is a complex containing a cation selected from the group consisting of scandium, titanium, manganese, rhenium, iron, copper, zinc, molybdenum, tungsten, and aluminum, and at least one anion selected from the group consisting of chlorine, bromine, and iodine.