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US 5,395,845 AGranted
Pyrethrinoid esters of thiazole alcohols
AssigneeRoussel Uclaf
InventorsMarc Benoit, Jean-Pierre Demoute, Christian Wehrey
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Abstract
In all possible stereoisomer forms and mixtures thereof of the formula ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is: ##STR2##
Claims11
A compound in all possible stereoisomer forms and mixtures thereof of the formula ##STR25## wherein R.sub.3 is:
- ##STR26## R.sub.2 is hydrogen, R.sub.1 is selected from the group consisting of alkyl, alkoxy and alkylthio of 1 to 4 carbon atoms optionally substituted by at least one halogen X is methyl or ethynyl and either A is:
- ##STR27## wherein Z.sub.1 is hydrogen and either Z.sub.2 is:
- ##STR28## wherein Z.sub.3 is hydrogen or halogen and T.sub.1 is selected from the group consisting of hydrogen, halogen, alkoxy and alkyl of 1 to 8 carbon atoms optionally substituted by a member of the group consisting of halogen, mono-, di- or trifuluoromethyl, cyano and phenyl optionally substituted by halogen and T.sub.2 is selected from the group consisting of hydrogen, halogen, alkoxy of 1 to 8 carbon atoms optionally substituted by halogen or alkyl of 1 to 8 carbon atoms substituted by a member of the group consisting of halogen, mono-, di- or trifluoromethyl, cyano and phenyl optionally substituted by halogen or T.sub.1 and T.sub.2 form together a cycloalkyl of 3 to 6 carbon atoms or:
- ##STR29## wherein B is oxygen or sulfur;
- or Z.sub.2 is:
- ##STR30## wherein a, b, c and d, individually are halogen or Z.sub.2 is:
- ##STR31## wherein D is selected from the group consisting of hydrogen or halogen, alkoxy of 1 to 8 carbon atoms, G is oxygen or sulfur and J is optionally unsaturated alkyl or cycloalkyl of up to 8 carbon atoms
- or A is:
- ##STR32## wherein U in any position on the benzene is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms and alkoxy of 1 to 8 carbon atoms, m is 0, 1 or 2 and when m is 2, the U substituents may be different and the other two of R.sub.1, R.sub.2 and R.sub.3 which are not:
- ##STR33## are individually selected from the group consisting of hydrogen, halogen, alkyl, alkenyl and alkynyl of up to 8 carbon atoms optionally substituted by at least one halogen, hydroxyl, O-alkyl, O-alkenyl or O-alkynl, CO.sub.2 -alkyl, CO.sub.2 -alkenyl, CO.sub.2 -alkenyl, S(O).sub.n -alkyl, S(O).sub.n -alkenyl or S(O).sub.n -alkynyl, n is 0, 1 or 2, of up to 8 carbon atoms optionally substituted by at least one halogen, aryl, O-aryl or thioaryl of up to 14 carbon atoms optionally substituted by at least one member of the group consisting of halogen, alkyl, alkenyl and alkynyl of up to 8 carbon atoms optionally substituted by at least one halogen and esterified, etherified or free hydroxy, heteroaryl and heeteroaryloxy, C.tbd.N, NH.sub.2 and NO.sub.2.
7 more elements
Dependencies are inferred from the claim text.