Maleimide polymers and contact lenses from such polymers
OwnerTeiji Kawano, Mitsuru Yokotainventors
Life of this patent
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Abstract
A maleimide polymer comprises units derived from a maleimide derivative represented by the following general formula (I): ##STR1## where R.sup.1 is a hydrogen atom or a methyl group, and R.sup.2 is an alkyl, alkenyl or aryl group, each of which groups is substituted by at least one organosiloxane group or fluorine atom, or comprises a copolymer of (1) a maleimide derivative represented by the formula (I) but in which R.sup.2 may be hydrogen or any optionally substituted aliphatic hydrocarbon or aryl group with (2) an alkyl or fluoroalkyl methacrylate or an organosiloxy styrene- or organosiloxy-(meth)acrylic acid derivative. The polymer material may be formulated into contact lenses high in oxygen permeability and having good mechanical properties.
Claims18
A polymer comprising units derived from a maleimide derivative represented by the formula (I):
- ##STR12## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2 is selected from the group consisting of an alkyl group, an alkenyl group and an aryl group, and R.sup.2 is substituted by at least one substituent selected from the group consisting of an organosiloxane group and a fluorine atom, wherein the units have a maleimide group only at one end.
A copolymer consisting essentially of units derived from comonomers having as a total monomer content:
- (a) about 5 to 95 parts by weight of the total monomer content of a maleimide derivative of the formula (I)':
- ##STR15## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group;
- wherein the maleimide derivative has a maleimide group only at one end and
- (b) about 95 to 5 parts by weight of the total monomer content of at least one (meth)acrylic acid ester selected from the group consisting of an alkyl(meth)acrylate and a fluoroalkyl(meth)acrylate.
A copolymer consisting essentially of units derived from comonomers having as a total monomer content:
- (a) about 5 to 95 parts by weight of the total monomer content of a maleimide derivative of the formula (I)', ##STR16## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2 ' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group;
- and
- (b) about 95 to 5 parts by weight of the total monomer content of at least one styrene derivative of the formula ##STR17## wherein:
- (1) B is selected from the group consisting of a direct bond, a phenyl group and a phenyl group substituted by at least one substituent selected from an organosiloxane group and a fluorine atom;
- (2) R.sup.3 is selected from the group consisting of a direct bond, an ester linkage and an amide linkage;
- (3) R.sup.4 is a C.sub.1-5 alkyl group;
- (4) X, Y and A are each selected from the group consisting of a C.sub.1-5 alkyl group, a phenyl group and a fluoroalkyl group;
- (5) m is from 0 to 200 inclusive;
- and
- (6) a, b and c are each independently of one another from 0 to 2 inclusive.
A copolymer consisting essentially of units derived from comonomers having as a total monomer content:
- (a) at least one maleimide derivative of the formula (I)' ##STR18## wherein R.sup.1 is selected from the group consisting of a methyl group and hydrogen atom, and R.sup.2 ' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group;
- and
- (b) at least one (meth)acrylic acid siloxanylalkyl ester of the structure ##STR19## wherein:
- (1) B is selected from the group consisting of a direct bond, a phenyl group and a phenyl group substituted by at least one substituent selected from an organosiloxane group and a fluorine atom;
- (2) R.sup.3 is selected from the group consisting of a direct bond, an ester linkage and an amide linkage;
- (3) R.sup.4 is a C.sub.1-5 alkyl group;
- (4) X, Y and A are each selected from the group consisting of a C.sub.1-5 alkyl group, a phenyl group and a fluoroalkyl group;
- (5) m is from 0 to 200 inclusive;
- and
- (6) a, b and c are each independently of one another from 0 to 2 inclusive;
- and R.sup.5 is selected from a hydrogen atom and a methyl group.
A contact lens comprising a polymer, which polymer comprises units derived from a maleimide derivative represented by the formula (I)':
- ##STR20## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2 is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group.
A contact lens comprising a copolymer consisting essentially of units derived from comonomers having as a total monomer content:
- (a) about 5 to 95 parts by weight of the total monomer content of a maleimide derivative of the formula (I)':
- ##STR23## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2 ' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group;
- and
- (b) about 95 to 5 parts by weight of the total monomer content of at least one (meth)acrylic acid ester selected from the group consisting of an alkyl(meth)acrylate and a fluoroalkyl(meth)acrylate.
A contact lens comprising a copolymer consisting essentially of units derived from comonomers having as a total monomer content:
- (a) about 5 to 95 parts by weight of the total monomer content of a maleimide derivative of the formula (I)' ##STR24## wherein R.sup.1 is selected from the group consisting of a methyl group and a hydrogen atom, and R.sup.2 ' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an aryl group;
- and
- (b) about 95 to 5 parts by weight of the total monomer content of at least one styrene derivative of the formula ##STR25## wherein:
- (1) B is selected from the group consisting of a direct bond, a phenyl group and a phenyl group substituted by at least one substituent selected from an organosiloxane group and a fluorine atom;
- (2) R.sup.3 is selected from the group consisting of a direct bond, an ester linkage and an amide linkage;
- (3) R.sup.4 is a C.sub.1-5 alkyl group;
- (4) X, Y and A are each selected from the group consisting of a C.sub.1-5 alkyl group, a phenyl group and a fluoroalkyl group;
- (5) m is from 0 to 200 inclusive;
- and
- (6) a, b and c are each independently of one another from 0 to 2 inclusive.
A contact lens comprising a copolymer consisting essentially of units derived from:
- (a) at least one maleimide derivative of the formula (I)' ##STR26## wherein R.sup.1 is selected from the group consisting of a methyl group and hydrogen atom, and R.sup.2 ' is selected from the group consisting of a hydrogen atom, an optionally substituted aliphatic hydrocarbon group and an optionally substituted aryl group;
- and
- (b) at least one (meth)acrylic acid siloxanylalkyl ester of the structure ##STR27## wherein:
- (1) B is selected from the group consisting of a direct bond, a phenyl group and a phenyl group substituted by at least one substituent selected from an organosiloxane group and a fluorine atom;
- (2) R.sup.3 is selected from the group consisting of a direct bond, an ester linkage and an amide linkage;
- (3) R.sup.4 is a C.sub.1-5 alkyl group;
- (4) X, Y and A are each selected from the group consisting of a C.sub.1-5 alkyl group, a phenyl group and a fluoroalkyl group;
- (5) m is from 0 to 200 inclusive;
- and
- (6) a, b and c are each independently of one another from 0 to 2 inclusive;
- and R.sup.5 is selected from a hydrogen atom and a methyl group.
Dependencies are inferred from the claim text.