Color photographic elements containing a combination of pyrazolone and pyrazoloazole couplers
AssigneeEastman Kodak Company
InventorsHans G. Ling, Drake M. Michno, Stephen Singer
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AssigneeEastman Kodak Company
InventorsHans G. Ling, Drake M. Michno, Stephen Singer
Estimating the term…
A photographic element including a support and first and second green-sensitive silver halide emulsion layers of different sensitivity, wherein the layer of higher sensitivity includes a two-equivalent magenta dye-forming coupler selected from the group consisting of a pyrazolone coupler having a structure according to formula I and a pyrazoloazole coupler having a structure according to formula II as set forth in the disclosure, and the layer of lower sensitivity includes a two-equivalent magenta dye-forming coupler selected from the group consisting of couplers defined by formulas I and II. The activity of the magenta dye-forming coupler present in the layer of lower sensitivity is less than the activity of the coupler present in the layer of higher sensitivity. The layers of higher and lower sensitivity do not comprise magenta couplers which are defined by the same formula.
A photographic element comprising a support and first and second green-sensitive silver halide emulsion layers of different sensitivity, wherein said first layer has a higher sensitivity than said second layer and comprises a two-equivalent magenta dye-forming coupler selected from the group consisting of a pyrazolone coupler having a structure according to formula I ##STR16## wherein R.sup.1 is an unsubstituted aryl group, or an aryl or pyridyl group substituted with one or more substituents selected from the group consisting of halogen atoms and alkyl, alkoxy, aryloxy, acyloxy, alkoxycarbonyl, aryloxycarbonyl, alkylsulfonyl, arylsulfonyl, sulfamoyl, sulfonamido, carbamoyl, carbonamido, ureido, nitro, cyano and trifluoromethyl;
A multicolor photographic element comprising a support bearing (a) a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, (b) a magenta dye image-forming unit comprising at least first and second green-sensitive silver halide emulsion layers of different sensitivity each having associated therewith at least one two-equivalent magenta dye-forming coupler, and (c) a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, said two-equivalent magenta dye-forming coupler associated with said green-sensitive emulsion layer having the higher sensitivity being selected from the group consisting of a pyrazolone coupler having a structure according to formula I ##STR27## wherein R.sup.1 is an unsubstituted aryl group, or an aryl or pyridyl group substituted with one or more substituents selected from the group consisting of halogen atoms and alkyl, alkoxy, aryloxy, acyloxy, alkoxycarbonyl, aryloxycarbonyl, alkylsulfonyl, arylsulfonyl, sulfamoyl, sulfonamido, carbamoyl, carbonamido, ureido, nitro, cyano and trifluoromethyl;
Dependencies are inferred from the claim text.