Epoxy resin compounds in admixture with glycidyl phosphorus compounds and heterocyclic polyamines
AssigneeSiemens Aktiengesellschaft
InventorsWolfgang von Gentzkow, Wolfgang Rogler, Dieter Wilhelm, Juergen Huber
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Abstract
The invention provides epoxy resin compounds for manufacturing prepregs and composite materials, which can be obtained inexpensively and have good processibility, and provide--without having to add flameproofing agents--virtually inflammable molded materials with a high glass transition temperature. The epoxy resin compounds contain the following constituents: (A) an aromatic and/or heterocyclic polyepoxide resin that is free of phosphorous, optionally in a mixture with an aliphatic epoxy resin; (B) an epoxy-group-containing phosphorous compound and (C) an aromatic polyamine as a curing agent.
Claims16
An epoxy resin composition for manufacturing prepregs and composite materials, comprising the following constituents:
- (A) an aromatic and/or heterocyclic polyglycidyl compound that is free of phosphorous;
- (B) an epoxy-group-containing phosphorous compound of the following structure:
- ##STR3## with m=0 or 1, n=0,1 or 2 and o=1, 2 or 3, where the following holds:
- m+n+o=3, and with p=0, 1 or 2;
- X signifies a free electron pair or an O- or S-atom linked via a double bond;
- R signifies an alkyl residue having 1 to 4 C-atoms;
- alkenyl residue having 2 to 3 C-atoms;
- aryl residue;
- aryl alkyl residue;
- dialkyl-amino residue or alkyl-aryl-amino residue or 3- trialkylsilylpropyl residue;
- R being linked directly or via O or S;
- R' denotes a bridge of O, S, phenylene, dioxyphenylene, dioxynaphthylene, (CH.sub.2).sub.r, O--(CH.sub.2).sub.r or O--(CH.sub.2).sub.r --O with r=1 to 3;
- and
- A.sup.1 and A.sup.2, which can be the same or different, denote a single bond or a bridge according to the grouping R';
- and
- (C) an aromatic polyamine as a curing agent of the following structure:
- ##STR4## where on each of the three aromatic partial structures, one of the residues R.sup.1 and R.sup.2 respectively denotes H and the other alkyl.
Dependencies are inferred from the claim text.