Alkaline light duty dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant, magnesium ions, chelator and buffer
AssigneeThe Procter & Gamble Company
InventorsThomas A. Cripe, Kofi Ofosu-Asante
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Abstract
A light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant, magnesium ions, a magnesium chelating agent, and a buffering agent to maintain the pH of the composition from about 8 to 10. High pH and magnesium ions of the composition provide good grease removal properties while maintaining mildness to the skin. The buffering agent and chelating agent of the composition provide superior physical and chemical stability during storage. The preferred type of dishwashing detergent composition is in the liquid form.
Claims20
A light-duty liquid or gel dishwashing detergent composition comprising, by weight:
- (a) from about 5% to 70% of a surfactant mixture comprising, by weight:
- (i) from about 70% to 100% of alkyl ethoxy carboxylates of the formula:
- RO(CH.sub.2 CH.sub.2 O).sub.x CH.sub.2 COO.sup.- M.sup.+
- wherein R is a C.sub.12 to C.sub.16 alkyl group, x ranges from 0 to about 10 and the ethoxylate distribution is such that, on a weight basis, the amount of material where x is 0 is less than about 20% and the amount of material where x is greater than 7 is less than about 25%, the average x is from about 2 to 4 when the average R is C.sub.13 or less, and the average x is from about 3 to 6 when the average R is greater than C.sub.13, and M is a cation;
- (ii) from 0% to about 15% of alcohol ethoxylates of the formula:
- RO(CH.sub.2 CH.sub.2 O).sub.x H
- wherein R is a C.sub.12 to C.sub.16 alkyl group and x ranges from 0 to about 10 and the average x is less than about 6;
- and
- (iii) from 0% to about 15% of soaps of the formula:
- RCOO.sup.- M.sup.+
- wherein R is a C.sub.11 to C.sub.15 alkyl group and M is a cation;
- (b) from about 0.1% to about 3% of magnesium ions;
- (c) a magnesium chelating agent which forms a soluble magnesium complex, having a log of formation constant, log K.sub.f, between about 1 and about 3.5;
- the agent being selected from the group consisting of sarcosine (N-methylglycine), bicine (bis(2-ethanol) glycine), N-2-hydroxyethyl iminodiacetic acid, N-(2,3-dihyroxypropyl) iminodiacetic acid, their alkali metal salts, and mixtures thereof, in an amount sufficient to prevent the formation of Mg(OH).sub.2 precipitates in the composition;
- and
- (d) sufficient alkalinity buffering agent selected from the group consisting of 2 amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl propanol, 2-amino-2-methyl-1,3-propanediol, tris-(hydroxymethyl) aminoethane, disodium glutamate, N-methyl diethanolamine, 1,3-diamino-2-propanol, N,N'-tetramethyl-1,3-diamino-2-propanol, N tris (hydroxymethyl) methyl glycine and mixtures thereof to maintain the pH of the composition between about 8 and 10 when diluted with water to about 0.1% to 0.4%, by weight.
A gel composition of claim I comprising from about 10% to 45% of the surfactant mixture.
Dependencies are inferred from the claim text.