Process for the preparation of a high molecular weight olefin polymer
AssigneeHoechst Aktiengesellschaft
InventorsAndreas Winter, Jurgen Rohrmann, Volker Dolle, Frank Kuber
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Abstract
A very active catalyst system for olefin polymerization comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 is hydrogen, R.sup.4 to R.sup.6 and alkyl or aryl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n is a single- or multi-membered chain, in which R' can also be a (substituted) hetero atom, and m+n is zero or 1.
Claims4
A metallocene compound of the formula I ##STR13## in which M.sup.1 is a metal of group IVb, Vb or VIB of the periodic table,
- R.sup.1 and R.sup.2 are identical or different and are a hydrogen atom, A c.sub.1 -C.sub.10 -alkyl group, a C.sub.1 -C.sub.10 -alkoxy group, aC.sub.6 -C.sub.10 -aryl group, a C.sub.6 -C.sub.10 aryloxy group, a C.sub.2 -C.sub.10 -alkenyl group, a C.sub.7 -C.sub.40 -arlalukd group, a C.sub.7 -C.sub.40 -alkylarly group, a C.sub.8 -C.sub.40 -arylakenyl group or a halogen atom,
- the radicals R.sup.3 are identical or different and are a hydrogen atom, a halogen atom, A c.sub.1 -C.sub.10 -alkyl group, which can be hydrogenated a C.sub.6 -C.sub.10 -aryl group, which can be halogenaed, or a --NR.sub.2.sup.10 --SR.sup.10 --OSiR.sub.3.sup.10, --SiR.sub.3.sup.10 or --PR.sub.2.sup.10 radical, in which R.sup.10 is a halogen atom, a C.sub.1 `r a C.sub.6 -C.sub.10 -aryl group,
- R.sup.4 to R.sup.6 are identical or different and have the meaning gien for R.sup.3, with the proviso that R.sup.4 and R.sup.6 are not hydrogen,
- R.sup.7 is ##STR14## .dbd.BR.sup.11, .dbd.AlR.sup.11, --Ge--, --Sn--, --O--, --S--, .dbd.SP, .dbd.SO.sub.2 .dbd.NR.sup.11, .dbd.COm .dbd.PR.sup.11 or .dbd.P(O)R.sup.11
- in which
- R.sup.11, R.sup.12 and R.sup.13 ar identical or different and are a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.10 -alkyl group, a C.sub.1 -C.sub.10 -fluoroalkyl group, a C.sub.6 -C.sub.10 -aryl grip, a C.sub.6 -C.sub.10 -fluoroaly group, a C.sub.1 -C.sub.10 -alkoxy group, a C.sub.2 -C.sub.10 -akenyl group, a C.sub.7 -C.sub.40 -arylalkyl group, a C.sub.8 -C.sub.4 alkylarly group, or R.sup.11 and R.sup.12, or R.sup.11 and R.sup.13, in each case with the atoms joining them, form a ring,
- M.sup.2 is silicon, germanium or tin,
- R.sup.8 and R.sup.9 are identical or different and have the meaning given for R.sup.11 and m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2.
Rac-dimethylsilyl(2-methyl-4,6-diisopropyl-1-idenyl.sub.2 zirconium dichloride.
Dependencies are inferred from the claim text.