Radiological system employing phosphors of different densities
AssigneeE. I. Du Pont de Nemours and Company
InventorsJacob Beutel, Sandra L. Issler, Daniel J. Mickewich
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Abstract
A pair of intensifying screens for use in high resolution radiography comprises a front screen comprising a phosphor with a density of no more than 5.5 g/cm.sup.3 and a back screen comprising a phosphor with a density of at least 6.0 g/cm.sup.3.
Claims9
A pair of radiographic intensifying screens comprising a front radiographic intensifying screen and a back radiographic intensifying screen capable of simultaneously exposing a photographic element interposed therebetween;
- wherein said front intensifying screen comprises a phosphor with a density of no more than 5.5 g/cm.sup.3 and said back intensifying screen comprises a phosphor with a density of at least 6.0 g/cm.sup.3.
A radiographic recording system comprising, in combination, a front intensifying screen, a back intensifying screen and a double emulsion film element in operative contact disposed therebetween;
- said front intensifying screen comprises a front phosphor layer coated on a support, wherein said front phosphor is selected from the group consisting of:
- (1) BaSO.sub.4 activated with lead;
- (2) Y.sub.2 O.sub.3 activated with gadolinium, cerium, bismuth, lead or combinations of the elements chosen from gadolinium, cerium, bismuth and lead;
- (3) DP.sub.2 O.sub.7 wherein D is hafnium or zirconium;
- (4) GFCl activated with europium where G represents barium or partial substitution thereof by an alkali metal, trivalent metal;
- or combination thereof;
- (5) YOX activated with cerium, gadolinium, bismuth or lead where X is fluorine, chlorine, or bromine;
- (6) Y.sub.2 O.sub.2 S activated with bismuth, cerium, gadolinium, lead or combinations of the elements chosen from bismuth, cerium, gadolinium and lead;
- (7) BaSiO.sub.3 activated with lead;
- (8) YPO.sub.4 activated with gadolinium, indium or combinations of gadolinium and indium;
- (9) Ca.sub.2 ZrSi.sub.4 O.sub.12 activated with lead;
- (10) BaZnSiO.sub.2 activated with lead;
- and
- (11) combination of phosphors chosen from (1)-(10);
- said back intensifying screen comprises a back phosphor layer coated on a support, wherein said back phosphor is selected from the group consisting of:
- (a) YTaO.sub.4, unactivated or activated with niobium, thulium, gadolinium, terbium or combinations of the elements chosen from niobium, thulium, gadolinium, terbium;
- (b) LuTaO.sub.4, unactivated or activated with niobium, thulium, gadolinium, terbium or combinations of the elements chosen from niobium, thulium, gadolinium and terbium;
- (c) a solid solution of (a) and (b);
- (d) GdTaO.sub.4, activated with terbium;
- (e) a solid solution of at least two of (a), (b) and (d);
- (f) any of (a) to (e) wherein up to 45 mole percent of the yttrium, lutetium or gadolinium is replaced by lanthanum;
- (g) any of (a) to (f) wherein up to 15 mole percent the yttrium, lutetium or gadolinium is replaced by ytterbium;
- and
- (h) any of (a), (b) and (c) wherein up to 15 mole percent of the yttrium or lutetium is replace by gadolinium;
- (i) Mg.sub.4 Ta.sub.2-2x Nb.sub.2x O.sub.9 :
- MyNa.sub.y' wherein
- M is at least one of potassium, rubidium, cesium;
- x is 5.times.10.sup.-4 to 0.5;
- y is at least 2.times.10.sup.-3, and
- y+y' is less than 1.0;
- (j) hafnium zirconium germanate unactivated or activated with titanium;
- (k) Hf.sub.1-z Zr.sub.z M.sub.y Ti.sub.x E.sub.e O.sub.a wherein
- E represents at least one of germanium and silicon;
- e is in the range of from greater than 1.times.10.sup.-3 to 0.1;
- M represents at least one alkali metal;
- x is in the range of from 3.times.10.sup.-4 to 1.0;
- y is in the range of 1.times.10.sup.-4 to 1.0;
- z is in the range of from 4.times.10.sup.-4 to 0.3;
- and
- a is sufficient to balance the charge.
- (l) CaWO.sub.4 ;
- (m) hafnium zirconium oxide containing at least one alkali metal and activated with titanium, at least one rare earth element or a combination of titanium and at least one rare earth element;
- (n) Li.sub.2 Hf.sub.1-x-y-z Zr.sub.z Sn.sub.y Ti.sub.x L.sub.w O.sub.3
- where L is at least one rare earth;
- w+x+y collectively are 0 to 0.2;
- and
- z is up to 0.2;
- (o) LnOX activated with terbium, thulium, cerium, ytterbium, or bismuth wherein Ln is gadolinium or lanthanum and X is fluorine, chlorine, or bromine;
- (p) Ln.sub.2 O.sub.2 S activated with at least one rare earth element, where Ln is gadolinium, lanthanum or lutetium.
Dependencies are inferred from the claim text.