Process for dyeing polymeric fibers
AssigneeShaw Industries Ltd.
InventorsDavid R. Kelly, Richard Castle, Christopher Bryant
Life of this patent
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Abstract
There is disclosed a process and a composition for dyeing polymeric fibers which have limited dye sites and/or difficult to penetrate chemical structures. Briefly stated, the process comprises the steps of contacting polymeric fibers with a dye composition comprising a disperse dye and a swelling agent. The fibers in contact with said dye composition are then preferably heated to a temperature and for a time sufficient to effect dispersion of a portion of said dye into said polymeric fibers. Subsequently, the fibers are treated to remove residual dye composition.
Claims34
A process for printing or space dyeing polyolefin fibers to produce discrete dyed and undyed regions comprising the steps of:
- providing polyolefin fibers, which polyolefin fibers have limited or no dye sites as part of the polymeric structure;
- contacting said polyolefin fibers at intermittent regions with a dye composition comprising a disperse dye and a swelling agent;
- applying dry heat to said polyolefin fibers in contact with said dye composition at a temperature at least above about 80.degree. F. less than the melting point of the polyolefin fibers for a time sufficient to effect dispersion of a portion of said disperse dye into said polyolefin fibers;
- removing residual dye composition from said polyolefin fibers.
A process for printing or space dyeing polypropylene fibers to produce discrete dyed and undyed regions comprising the steps of:
- providing polypropylene fibers;
- contacting said fibers at intermittent regions with a dye paste comprising a disperse dye, a swelling agent, a thickener, and an acid;
- applying dry heat to said fibers in contact with said dye composition at a temperature above about 280.degree. F. for at least about 15 seconds to thereby effect dispersion of a portion of said dye into said fibers;
- and
- washing said fibers to remove residual dye composition.
A process for dyeing polypropylene fibers comprising the steps of:
- providing polypropylene fibers;
- contacting said fibers with a dye paste comprising a disperse dye, a swelling agent, a thickener, and an acid, the dye paste having a viscosity between about 800 and about 3000 centipoise at 80.degree. F. as measured by a Brookfield Viscosimeter with a No. 3 spindle;
- heating said fibers in contact with said dye paste at a temperature above about 280.degree. F. for at least about 15 seconds to thereby effect dispersion of a portion of said dye into said fibers;
- and
- washing said fibers to remove residual dye paste.
A process for dyeing polyolefin fibers comprising the steps of:
- providing polyolefin fibers, which polyolefin fibers have limited or no dye sites as part of the polymeric structure;
- contacting said polyolefin fibers with a dye composition comprising a disperse dye and a swelling agent comprising a mixture of n-cyclohexyl-2-pyrrolidone and diethylene glycol;
- applying dry heat to said polyolefin fibers in contact with said dye composition at a temperature at least above about 80.degree. F. less than the melting point of the polyolefin fibers for a time sufficient to effect dispersion of a portion of said disperse dye into said polyolefin fibers;
- removing residual dye composition from said polyolefin fibers.
Dependencies are inferred from the claim text.