Hydrogen recovery by adsorbent membranes
AssigneeAir Products and Chemicals, Inc.
InventorsMadhukar B. Rao, Shivaji Sircar, Joseph M. Abrardo, William F. Baade
Life of this patent
Estimating the term…
Abstract
A composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate is operated in series with a pressure swing adsorption (PSA) system and the PSA reject gas is used as a sweep gas to improve membrane performance. The integrated membrane-PSA system is particularly useful for recovering high-purity hydrogen from a mixture of hydrogen and hydrocarbons, and is well-suited for integration with a steam-methane reformer.
Claims14
A method for the recovery of one or more primary components from a gaseous feed mixture comprising said primary components and one or more secondary components, wherein said secondary components are more strongly adsorbed on an adsorbent material than said primary components, said method comprising:
- (a) passing said feed mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator a nonpermeate intermediate product stream enriched in said primary components, wherein portions of said secondary components are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase;
- (b) withdrawing from the permeate side of said membrane a permeate comprising said secondary components;
- (c) separating said nonpermeate intermediate product stream into a high-purity product stream comprising said primary components and a reject stream comprising an additional portion of said secondary components;
- and
- (d) passing at least a portion of said reject stream across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of said primary components and increasing the permeation rate of said secondary components through said membrane.
A method for the production of hydrogen from a methane-containing feed gas and a gas mixture containing hydrogen and hydrocarbons, wherein said method comprises:
- (a) passing said gas mixture into a separator containing a composite semipermeable membrane comprising microporous adsorbent material supported by a porous substrate, said membrane having a feed side and a permeate side, and withdrawing from said separator an intermediate product stream enriched in hydrogen, wherein portions of said hydrocarbons are selectively adsorbed by said microporous adsorbent material and diffuse from the feed side to the permeate side of said membrane as an adsorbed fluid phase;
- (b) withdrawing from the permeate side of said membrane a permeate comprising said hydrocarbons;
- (c) reforming a portion of said methane-containing feed gas in a steam-methane reformer to produce a synthesis gas comprising hydrogen, carbon oxides, water, and unreacted methane, and combining said synthesis gas with said intermediate product stream;
- (d) passing the resulting combined stream of step (c) into a pressure swing adsorption system wherein hydrocarbons and carbon oxides are selectively adsorbed, and withdrawing therefrom a high purity hydrogen product and a reject stream comprising hydrocarbons and carbon oxides;
- and
- (e) passing the remaining portion of said methane-containing feed gas across the permeate side of said membrane as a sweep gas and withdrawing from said separator a sweep gas/permeate effluent stream, thereby increasing the recovery of hydrogen and increasing the permeation rate of hydrocarbons through said membrane.
Dependencies are inferred from the claim text.