# US 5,353,136 A · Ferroelectric liquid crystal with positive dielectric anisotropy, chevron structure and grey scale

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- Number: US 5,353,136 A
- Document ID: US5353136A
- Status: Granted
- Kind: A
- Application number: 07/778,175
- Filed: 1991-12-13
- Granted: 1994-10-04
- Earliest claimed: 1989-06-17
- Assignees: Hoechst Aktiengesellschaft
- Inventors: Claus Escher; Hans-Rolf Dubal; Takamasa Harada; Gerhard Illian; Mikio Murakami; Dieter Ohlendorf
- Web page: https://patentgrep.com/patent/US5353136A

## CPC

- G02F 1/141: using ferroelectric liquid crystals
- C09K 19/0225: {Ferroelectric}
- C09K 19/3463: {Pyrimidine with a carbon chain containing at least one asymmetric carbon atom, i.e. optically active pyrimidines}
- G02F 1/1416: {Details of the smectic layer structure, e.g. bookshelf, chevron, C1 and C2}
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

A method of driving a ferroelectric liquid crystal element which enlarges the effective cone angle. A ferroelectric liquid crystal is held between two substrates such that the helix is suppressed and a chevron layer structure is present. The ferroelectric material has a positive dielectric anisotropy. A first pulse is applied which causes switching from one state to the other, and a subsequent smaller AC pulse is applied which does not cause switching. The second pulse voltage control the effective cone angle, enabling grey scale.

## Claims

### Claim 1

A process for enlarging the effective cone angle in a liquid crystal element comprising a housing, which contains an interstice bordered by a sealing material between two transparent sheets, and additionally at least one polarization film, at least one rubbed orientation layer, furthermore two electrodes on both inner surfaces of the transparent sheets and a liquid-crystalline, ferroelectric smectic material present in the interstice, wherein the liquid-crystalline material firstly forms a chevron structure, and formation of a helix is suppressed, and secondly has spontaneous polarization and a positive dielectric anisotropy, said process comprising firstly applying a pulse of a high voltage (V.sub.s) and a length .tau..sub.s which has the effect that the molecules can be switched from one state to the other, and secondly applying subsequent smaller alternating current pulses (V.sub.ac), which have a length .tau..sub.ac, which is the same or shorter than the length of the first pulse, and which do not allow further switching.

### Claim 2 (depends on 1)

The process as claimed in claim 1, wherein the liquid-crystalline material forms an S.sub.c.sup.*, S.sub.F.sup.*, S.sub.G.sup.*, S.sub.I.sup.* or S.sub.J.sup.* phase.

### Claim 3 (depends on 1)

The process as claimed in claim 1, wherein the liquid-crystalline material has an N.sup.* phase in a temperature range above the ferroelectric phase.

### Claim 4 (depends on 1)

The process as claimed in claim 1, wherein grey steps can be controlled with the aid of the effective value of the voltage.