# US 5,352,817 A · Cationic silicones

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- Number: US 5,352,817 A
- Document ID: US5352817A
- Status: Granted
- Kind: A
- Application number: 07/975,335
- Filed: 1992-11-16
- Granted: 1994-10-04
- Earliest claimed: 1990-06-29
- Assignees: Karlshamns AB
- Inventors: James P. McCarthy; George H. Greene; Anthony G. DeWar
- Web page: https://patentgrep.com/patent/US5352817A

## CPC

- D06M 15/6436: {containing amino groups}
- A61K 8/895: containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
- A61K 8/898: containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
- A61Q 5/12: Preparations containing hair conditioners
- A61Q 19/00: Preparations for care of the skin
- C03C 25/40: Organo-silicon compounds
- C04B 41/009: {characterised by the material treated}
- C04B 41/4584: {Coating or impregnating of particulate or fibrous ceramic material (C04B20/10, C04B35/628 take precedence)}
- C04B 41/4944: {containing atoms other than carbon, hydrogen, oxygen, silicon, alkali metals or halogens, e.g. N-silyldisilazane: Image}
- C04B 41/495: {applied to the substrate as oligomers or polymers}
- C07F 7/0838: {Compounds with one or more Si-O-Si sequences (compounds with a ring containing only alternating Si and O atoms, i.e. cyclosilanes C07F7/21)}
- C08G 77/388: containing nitrogen
- C11D 3/3742: {Nitrogen containing silicones}
- D06M 7/00: {Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins (D06M10/00 takes precedence; treating fibres or filaments made of glass, mineral -, or slag wool C03C; carbon fibres D01F11/10)}
- D06M 2200/40: Reduced friction resistance, lubricant properties; Sizing compositions
- Y10S 516/01: Wetting, emulsifying, dispersing, or stabilizing agents
- Y10T 428/2962: Silane, silicone or siloxane in coating
- Y10T 442/2328: Organosilicon containing
- D06M: TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- C07F: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM (metal-containing porphyrins C07D487/22)
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A cationic silicone compound which can be employed in a variety of environments, such as a fiber lubricant, textile fabric softener, hair conditioner, and skin conditioner is formed from an aminosilicone compound which has the following Formula (I): ##STR1## wherein a, b, and c are 0-300; d is 0-4, preferably 1 or 2; R.sub.1 comprises hydrogen, an alkyl, aryl, alkynyl, alkenyl, oxyalkylene group which may be unsubstituted or substituted with P,N, or S moieties; R.sub.2 is defined the same as R.sub.1 and can also be a carboxylic acid residue preferably a fatty acid residues, with the proviso that where R.sub.2 is a carboxylic acid residue, the R.sub.1 attached to the terminal N is hydrogen; R.sub.3 is defined the same as R.sub.2 and can also be alkoxy, aryloxy or alkyloxyalkylene groups; R.sub.4 is defined the same as R.sub.3 and can also be an amino-substituted alkyl group; Z.sub.1 and Z.sub.2 can be the same or different and comprise an alkyl, aryl, alkenyl or alkynyl group with the proviso that if b is 0, then at least one of the R.sub.4 groups comprises an amino-substituted alkyl group. In particular, the aminosilicone is quaternized using known quarternizing agents, e.g., alkylation reagents.

## Claims

### Claim 1

An aminosilicone compound represented by the following formula: ##STR25## wherein a and c are 0-300; b is 1-300;
d is 0-4;
R.sub.1 and R.sub.2, both comprise an oxyalkylene group substituted with P,N, or S moieties;
R.sub.3 and R.sub.4 are the same or different and comprise an alkyl group or an alkyloxyalkylene group;
Z.sub.1 and Z.sub.2 are the same or different and comprise an alkyl group.

### Claim 2 (depends on 1)

The aminosilicone compound of claim 1 wherein at least one R.sub.3 comprises an alkyloxyalkylene group.

### Claim 3 (depends on 2)

The aminosilicone compound of claim 2 where d is 1.
