# US 5,352,643 A · High strength alumina and process for producing same

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- Number: US 5,352,643 A
- Document ID: US5352643A
- Status: Granted
- Kind: A
- Application number: 07/970,615
- Filed: 1992-11-03
- Granted: 1994-10-04
- Earliest claimed: 1992-11-03
- Assignees: Board of Control of Michigan Technological University
- Inventors: James M. Staehler; William W. Predebon; Bruce J. Pletka
- Web page: https://patentgrep.com/patent/US5352643A

## CPC

- C04B 35/645: Pressure sintering
- C04B 35/111: Fine ceramics
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

A vacuum hot pressed alumina material having small, isometric grains; a uniform distribution thereof; relatively low, predominantly transgranular porosity; and a density approaching the theoretical density of pure alumina produced by vacuum hot pressing alumina powder which contains at least 98.0% alumina, is substantially free of any sintering aids or any other additives, and has a median particle size less than about 3 microns, in a vacuum hot press operated at a temperature of at least about 1350.degree. C. and a pressure of at least 28 MPa (3500 PSI) for a sintering period of at least 1.5 hours. The vacuum hot pressed alumina material also has compressive strength, flexural strength, impact strength, and wear resistance superior to that for most conventional sintered alumina materials.

## Claims

### Claim 1

A vacuum hot pressed alumina material free of sintering agents and organic contaminants and having a compressive fracture strength greater than about 4,400 MPa at a strain rate of 10.sup.-4 s.sup.-1.

### Claim 2 (depends on 1)

A material according to claim 1 having a compressive fracture strength greater than about 5,100 MPa at a strain rate of 10.sup.-4 s.sup.-1.

### Claim 3 (depends on 1)

A material according to claim 1 having a compressive fracture strength greater than about 5,566 MPa at a strain rate of 10.sup.-4 s.sup.-1.

### Claim 4

A vacuum hot pressed alumina material free of sintering agents and organic contaminants and having a compressive fracture strength greater than about 6,700 MPa at a strain rate of 10.sup.3 s.sup.-1.

### Claim 5 (depends on 4)

A material according to claim 4 having a compressive fracture strength greater than about 7,800 MPa at a strain rate of 10.sup.3 s.sup.-1.

### Claim 6 (depends on 4)

A material according to claim 4 having a compressive fracture strength greater than about 8,400 MPa at a strain rate of 10.sup.3 s.sup.-1.

### Claim 7 (depends on 1)

A material according to claim 1 having a mean grain size less than about 3.0 microns.

### Claim 8 (depends on 1)

A material according to claim 1 having a mean grain size less than about 2.0 microns.

### Claim 9 (depends on 1)

A material according to claim 1 having a mean grain size less than about 1.5 microns.

### Claim 10 (depends on 1)

A material according to claim 1 having a mean form factor greater than about 0.75.

### Claim 11 (depends on 1)

A material according to claim 1 having a mean form factor greater than about 0.80.

### Claim 12 (depends on 1)

A material according to claim 1 having a mean form factor greater than about 0.86.

### Claim 13

A vacuum hot pressed alumina material free of sintering agents and organic contaminants and having a spall strength greater than about 0.75 GPa.

### Claim 14 (depends on 13)

A material according to claim 13 having a spall strength greater than about 1.0 GPa.

### Claim 15 (depends on 13)

A material according to claim 13 having a spall strength greater than about 1.2 GPa.

### Claim 16

A vacuum hot pressed alumina material free of sintering agents and organic contaminants and having a flexural strength greater than about 780 MPa.

### Claim 17 (depends on 16)

A material according to claim 16 having a flexural strength greater than about 900 MPa.

### Claim 18

A vacuum hot pressed alumina material free of sintering agents and organic contaminants and having a Young's modulus greater than about 350 GPa.

### Claim 19 (depends on 18)

A material according to claim 18 having a Young's modulus greater than about 400 GPa.