# US 5,352,528 A · Laminated pane > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,352,528 A - Document ID: US5352528A - Status: Granted - Kind: A - Application number: 08/057,832 - Filed: 1993-05-07 - Granted: 1994-10-04 - Earliest claimed: 1992-05-07 - Assignees: Saint-Gobain Vitrage International - Inventors: Anne L'Her; Pascal Chartier; Joel Robineau - Web page: https://patentgrep.com/patent/US5352528A ## CPC - B32B 27/30: comprising vinyl {(co)polymers; comprising acrylic (co)polymers} - B32B 17/10018: {comprising only one glass sheet} - B32B 17/10036: {comprising two outer glass sheets} - B32B 17/10688: {Adjustment of the adherence to the glass layers} - B32B 17/10788: {containing ethylene vinylacetate} - Y10T 428/31645: Next to addition polymer from unsaturated monomers - Y10T 428/31649: Ester, halide or nitrile of addition polymer - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract Laminated pane, comprising at least one glass sheet, and at least one film of plastics material. Between the film of plastics material and the glass sheet there Is disposed an adhesive film of a material having the property of an adhesion to the glas. The adhesive film is selected so that it adheres more strongly to the glass than to the plastics material. ## Claims ### Claim 1 A laminated pane including at least one glass sheet and at least one film of plastics material comprising PVC and having a transparency which is stable with respect to aging and weathering and having an energy absorption suitable for a safety pane, wherein there is disposed an adhesive film between the glass sheet and film of plastics material, said adhesive film having a greater adhesion to the glass than to the film of plastics material, and wherein said adhesive film comprises a terpolymer comprised of ethylene, either vinyl acetate or acrylic ester, and maleic anhydride. ### Claim 2 (depends on 1) The laminated pane according to claim 1, wherein the percentage by weight of maleic anhydride in said adhesive film is between about 0.1 and 5%. ### Claim 3 (depends on 2) The laminated pane according to claim 2, wherein the terpolymer is obtained by statistical polymerization of ethylene, vinyl acetate and maleic anhydride. ### Claim 4 (depends on 2) The laminated pane according to claim 2, wherein the terpolymer contains 15 to 35% by weight of vinyl acetate. ### Claim 5 (depends on 2) The laminated pane according to claim 2, wherein the terpolymer contains 20 to 30% by weight of vinyl acetate. ### Claim 6 (depends on 2) The laminated pane according to claim 2, wherein the film of plastics material further comprises at least one plasticizer and/or stabilizer. ### Claim 7 (depends on 1) The laminated pane according to claim 1, comprising two glass sheets, between which is disposed, on either side of the film of plastics material, two adhesive films. ### Claim 8 (depends on 7) The laminated pane according to claim 7, wherein the film of plastics material has a thickness lying between 250 and 1,000 micrometers. ### Claim 9 (depends on 7) The laminated pane according to claim 7, wherein the adhesive film has a thickness of between 20 and 70 micrometers. ### Claim 10 (depends on 7) The laminated pane according to claim 7, further comprising at least one sheet of rigid plastics material disposed between a glass sheet and an adhesive film. ### Claim 11 (depends on 10) The laminated pane according to claim 10, wherein said rigid plastics material is selected from the group consisting of polycarbonate and polymethyl methacrylate. ### Claim 12 A laminated pane comprising at least one glass sheet, at least one adhesive film, and at least one film of plastics material, wherein said adhesive film is disposed between said glass sheet and said film of plastics material, and wherein said adhesive film has a greater adhesion to the glass than to the film of plastics material and comprises a terpolymer of ethylene, vinyl acetate, and maleic anhydride, the maleic anhydride being present in the terpolymer in the amount of from about 0.1 to 5% by weight based on the terpolymer and wherein said plastics material has a transparency which is stable with respect to aging and weathering and has an energy absorption suitable for a safety pane. ### Claim 13 A laminated pane including a composite between two glass sheets, wherein the composite comprises a plastic sheet comprising PVC and having a transparency which is stable with respect to aging and weathering and having an energy absorption suitable for a safety pane disposed between two adhesive films, said adhesive films having a greater adhesion to the glass than to the film of plastics material, wherein each of said adhesive films are composed of a terpolymer including 0.1 to 5% of maleic anhydride, by weight based on the terpolymer. ### Claim 14 (depends on 13) The laminated pane according to claim 13, wherein the terpolymer includes 0.5 to 2% of maleic anhydride, by weight based on the terpolymer. ### Claim 15 A laminated pane including a glass sheet and sheet of rigid plastics material disposed on opposite sides of a composite structure, said composite structure comprising at least one adhesive film and a film comprising a plastics material, said plastics material having a transparency stable with respect to aging and weathering, and having an energy absorption suitable for a safety pane, and wherein said adhesive is disposed between said glass sheet and said film comprising a plastics material and said adhesive has a greater adhesion to the glass than to the film of plastics material and comprises a terpolymer including 0.1 to 5% maleic anhydride by weight based on the terpolymer. ### Claim 16 (depends on 15) The laminated pane according to claim 15, wherein the rigid plastics material is selected form the group consisting of polycarbonate and polymethyl methacrylate. ### Claim 17 (depends on 16) The laminated pane according to claim 16, wherein the film comprising a plastics material is a film including PVC. ### Claim 18 (depends on 13) A vehicle windshield according to claim 13, wherein said plastics material further comprises 20 to 50% by weight of at least one plasticizing resin. ### Claim 19 (depends on 13) A window for a building according to claim 13, wherein said plastics material further comprises 20 to 50% by weight of at least one plasticizing resin. ### Claim 20 (depends on 12) The laminated pane according to claim 12, wherein said plastics material comprises PVC.