# US 5,352,495 A · Treatment of a surface by laser energy > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,352,495 A - Document ID: US5352495A - Status: Granted - Kind: A - Application number: 08/000,721 - Filed: 1993-01-06 - Granted: 1994-10-04 - Earliest claimed: 1989-02-16 - Assignees: The Wiggins Teape Group Limited - Inventors: Andrew R. Henderson; Robert Jones - Web page: https://patentgrep.com/patent/US5352495A ## CPC - B23K 26/0734: {into an annular shape} - B23K 26/0846: {for moving elongated workpieces longitudinally, e.g. wire or strip material} - B41M 5/26: Thermography (B41M5/20, B41M5/24 take precedence); {Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used (B23K takes precedence; thermographic or photothermographic systems using noble metal compounds G03C1/494)} - D21H 25/04: Physical treatment, e.g. heating, irradiating (D21H25/18 takes precedence; dryer section of machines for making continuous webs of paper D21F5/00) - B23K: SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM - B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P) - D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR ## Abstract In treating the surface of a material with laser energy by sweeping a laser beam over the surface, a substantial uniformity of energy delivery is achieved across a major portion of the transverse width of the beam by using an unfocussed beam of a ring mode configuration and preferably one having an outer ring with at least some degree of interior fill as is achieved by a laser beam continuing TEM.sub.00 and TEM.sub.01 * modes. The specification discusses various beam configurations. The specification introduces the concept of "exposure integration" which is a function not only of the beam profile in the sweep direction but of the rate of sweep. An exposure duration for any scanned point of not more than 10 milliseconds is suggested. The application of the invention is particularly described with reference to marking the surface of paper. ## Claims ### Claim 1 A method of treating the surface of a paper material with laser energy comprising the steps of providing a relative scanning movement between a surface and an axis of a laser beam in a scan direction where: the laser beam is unfocussed at the surface, the beam has a cross-section at the surface with a width transverse to the direction of scan, the cross-section of the beam at the surface comprises a ring-shaped propagation mode and exhibits an irradiance distribution distinctive of the propagation mode structure of the beam, and relatively moving the beam and the surface in the scan direction such that a scanning velocity of the beam relative to the surface is such that at any scanned point on the surface, thermal energy is generated which is a function of an integral of the beam irradiance distribution acting at that point as the beam traverses that point. ### Claim 2 (depends on 1) The method as claimed in claim 1 in which said ring mode structure is circularly symmetrical. ### Claim 3 (depends on 2) The method as claimed in claim 2 in which the irradiance distribution of said mode structure comprises an outer ring and a central peak. ### Claim 4 (depends on 3) The method as claimed in claim 3 in which the mode structure comprises a combination of TEM.sub.00 and TEM.sub.01 * modes. ### Claim 5 (depends on 1) The method as claimed in claim 1 in which the laser beam operates at a power below a level at which significant charring occurs. ### Claim 6 (depends on 1) The method as claimed in claim 1 in which the duration of laser beam exposure is not more than 10 milliseconds. ### Claim 7 (depends on 1) The method as claimed in claim 1 wherein beam width transverse to the scan direction and beam length in the scan direction are essentially the same. ### Claim 8 (depends on 1) The method as claimed in claim 1 wherein beam width transverse to the direction of scan is greater than a millimeter. ### Claim 9 (depends on 1) The method as claimed in claim 1 wherein the scanning velocity is selected such that the material surface is free of response to peaks of the propagation mode structure of the beam profile. ### Claim 10 (depends on 9) The method as claimed in claim 9 wherein the scanning velocity is selected such that the beam profile has a duration at the point of less than about 10 milliseconds. ### Claim 11 A method of treating the surface of a paper material with laser energy comprising the steps of providing a relative scanning movement between a surface and an axis of a laser beam in a scan direction where: the laser beam is unfocussed at the surface, the beam has a cross-section at the surface with a width transverse to the direction of scan, the cross-section of the beam at the surface comprises a ring-shaped propagation mode and exhibits an irradiance distribution distinctive of the propagation mode structure of the beam, and relatively moving the beam and the surface in the scan direction such that a scanning velocity of the beam relative to the surface is such that at any scanned point on the surface, exposure duration is sufficiently short to ensure that the point responds to an integrated energy derived from the beam irradiance distribution acting at that point as the beam traverses that point. ### Claim 12 (depends on 11) The method as claimed in claim 11 in which said ring mode structure is circularly symmetrical. ### Claim 13 (depends on 12) The method as claimed in claim 12 in which the irradiance distribution of said mode structure comprises an outer ring and a central peak. ### Claim 14 (depends on 13) The method as claimed in claim 13 in which the mode structure comprises a combination of TEM.sub.00 and TEM.sub.01 * modes. ### Claim 15 (depends on 11) The method as claimed in claim 11 in which the laser beam operates at a power below a level at which significant charring occurs. ### Claim 16 (depends on 11) The method as claimed in claim 11 in which the duration of laser beam exposure for any scanned point is not more than 10 milliseconds. ### Claim 17 (depends on 11) The method as claimed in claim 11 wherein beam width transverse to the scan direction and beam length in the scan direction are essentially the same. ### Claim 18 (depends on 11) The method as claimed in claim 11 wherein beam width transverse to the direction of scan is greater than a millimeter. ### Claim 19 (depends on 18) The method as claimed in claim 18 wherein the laser beam has a diameter and wherein the scanning velocity, in meters per second, exceeds 1/10 of the laser beam diameter, measured in millimeters. ### Claim 20 (depends on 12) The method as claimed in claim 12 wherein the scanning velocity is selected such that the material surface is free of response to peaks of the propagation mode structure of the beam profile. ### Claim 21 (depends on 20) The method as claimed in claim 20 wherein the scanning velocity is selected such that the beam profile has a duration at the point of less than about 10 milliseconds. ### Claim 22 (depends on 21) The method as claimed in claim 21 wherein the laser beam has a diameter and wherein the scanning velocity, in meters per second, exceeds 1/10 of the laser beam diameter, measured in millimeters.